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Sackmann, 1971) , stilbenes (Haas et al., 1974), menthones (Van de Witte et al., 1999, 1998; Brehmer et al., 1998), diarylethenes (Yamaguchi et al., 2001; Denekamp and Feringa, 1998), overcrowded alkenes (Eelkema et al., 2006; van Delden et al., 2003; Feringa et al., 1995), and ugides (Sagisaka and Yokoyama, 2000). When the photochromic compounds with chiral groups are dissolved in a nematic LC, phototuning of the induced helical structure can be easily achieved by the use of suitable light, leading to a difference in HTP between photoisomers through photochemical change in their molecular shapes. Azobenzene molecules undergo reversible trans cis photoisomerization by irradiation of light with appropriate wavelength (Ross and Blank, 1971), and when a chiral azobenzene molecule is doped in Ch LCs, its HTP can be changed by reversible photoisomerization. Thus, according to Eq. 10.2, the helical pitch can be controlled through reversible photoisomerization. Azobenzene systems represent very attractive phototriggers in Ch LCs, thanks to their resistance to photofatigue, the simplicity of the molecules, and the ease of modi cation of their molecular structures. This chapter rst describes helical twisting ability of chiral azobenzene compounds by focusing the structural effects on HTP as well as photochemical change in HTP, and then phototuning of helical structures of Ch LCs through the trans cis photoisomerization of the chiral azobenzene compounds for applications to optical devices.



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Now if the solid screen bores you, it s possible to use the bkgd() function to fill each character space on the screen with a given character. That s because the argument to the bkgd() function is a chtype character. The NCurses chtype is a special type of variable that includes both an attribute and a character. So, if you like, you can specify a single character as the background attribute for a window. Modify the BGCOLOR1.C source code and change line 9 to read:

bkgd( . );

public class PreconfiguredEx : MarshalByRefObject, IPricing { public override object InitializeLifetimeService() { return null; } }





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Figure 10.2 shows chiral and nonchiral azobenzene compounds. A Ch phase was induced by mixing each chiral azobenzene compound in a host nemaic LC. In such a binary system consisting of a nonchiral host nematic LC and a chiral compound, the reciprocal of the helical pitch (1/p) is known to increase linearly with the concentration (c) of the chiral compound at lower c, and HTP of the chiral compound can be de ned as the slope of the 1/p versus c (Eq. 10.2). Figure 10.3 shows changes in the 1/p of the induced Ch LCs as a function of c in the dark and under ultraviolet (UV) light (365 nm) to cause trans cis photoisomerization of the chiral azobenzene compounds. The helical pitch was determined by Cano s method (Bahr et al., 1991). The 1/p increased almost linearly with the increase of c. HTP of the chiral azobenzenes was on the order of azo-1Wazo-2Wazo-3: 23 102 for azo-1, 6.6 102 for azo-2, and 2.6 102 (mm 1 mol 1 g of E44) for azo-3, respectively (Kurihara et al., 2000). HTP was decreased by increasing the distance between azobenzene group and chiral center. The distance between the azo group and the chiral center is one of the factors in uencing the twisting ability. A decrease in the 1/p was brought about photochemically by UV irradiation. This result means that the trans to cis photoisomerization of these azobenzene compounds caused the decrease in the helical pitch length.

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Upon running the program, you ll see the window s background filled with dots or periods. They appear between words as well because it s the dot that defines the window s background attribute. To combine the dot and the color pair, modify line 9 to read:

bkgd(COLOR_PAIR(1) | . );

S811(or R811)

The | in the code is the logical OR. It takes the value of COLOR_PAIR(1) and logically ORs it with the character code for a period. You can also use the logical OR to apply other attributes or characters for the bkgd() function. (See Appendix C for more information on the chtype variable in NCurses.)

When a client accesses an instance that is no longer accessible because its lease has timed out, the client receives a RemotingException:

The bkgd() function affects all attributes and unused character places on the screen. Any text you ve written stays on the screen as text; only the attributes are changed, as Listing 3-7 demonstrates:

N=N (K 33 C Ch 43 C I)

3

Unhandled Exception: System.Runtime.Remoting.RemotingException: Object </6ddffc7/1.rem> has been disconnected or does not exist at the server.

Azo-1

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