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It consists of azobenzene-containing building blocks connected by H-bonds forming a main-chain polymer as depicted in Fig 24e The lms prepared by casting exhibited 15-nm deep SRG with grating spacing of 780 nm upon 40-min holographic irradiation using p-polarized beams of moderate intensity of 100 mW/cm2 The authors report that the induced structures are thermally stable up to 1001C Moreover, the mechanism of thermal erasing of the grating has been investigated by in situ temperature-dependent FT IR spectroscopy It has been shown that the amide groups change from Z into E conformation by heating to 1501C, which breaks quadruple hydrogen bonds Such disassembly of supramolecular polymer leads to the disappearance of the surface relief structure As the gratings inscription in the H-bonded main-chain supramolecular polymer was very ineffective, the authors developed an azobenzene-containing supramolecular side-chain polymer, as it is shown in Fig 24f (Gao et al, 2007a).



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Supposedly, if the screen flashes, OK is returned. flash() returns ERR otherwise. Both OK and ERR are defined in NCURSES.H. Do not rely upon the ERR return value to determine whether or not the terminal really did flash.

[Qui03] [Ram02] [Rie97] [Rog95] [Rox04]

A 300-nm deep grating was inscribed in this material under similar irradiation conditions Note that at the same time the photoorientation ability of the azobenzene was a few times smaller than in the supramolecular main-chain polymer The induced SRGs are thermally stable up to 1201C A series of.





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flash() is used mostly an alternative to the beep() function, specifically designed for situations where noise is undesirable or for the hearing impaired. This function doesn t work if the terminal has been configured not to flash. On most monitors, the flash is made of the current text foreground color. Some terminals may both beep and flash the screen when the flash() function is used.

flash();

[Sar02]

[Irie, 1993]

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 #include <ncurses.h> int main(void) { initscr(); addstr( Press any key to flash:\n ); refresh(); getch(); flash(); addstr( Thanks!\n ); refresh(); getch(); endwin(); return 0; }

Sample output:

HEAM [Menzel, 1995]

Press any key to flash:

[Sar03]

(Press Enter.) The screen winks at you!

4.4 2.5

Thanks!

24.09.2004 20:26

16 (resp. 10a) 2.7 (resp 2.7)

3, beep()

flushinp()

a in 1C per mol% azo in the polymer. NIPA poly(N-isopropylacrylamide), HEAM hydroxyethylacrylamide, HPMC hydroxypropyl methylcellulose. N.A. not available.

Seti@Home: The Search for Extraterrestrial Intelligence, 2004 http://setiathome.ssl.berkeley.edu/ [Sev04] D. Sevilla: The CORBA & CORBA Component Model (CCM) Page, 2004 http://ditec.um.es/~dsevilla/ccm/ [Sor02]

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The flushinp() function clears the keyboard input buffer, or queue, ensuring that no characters are waiting to be read.

int flushinp(void);

a more polar azobenzene with 4umethoxyethyloxy substituent. not shown in the ref, our estimate uses LCST of c.a. 551C for the unmodi ed chain.

Flushing input is recommended for situations where the user is posed a vital question. By using flushinp() you ensure that no stray keys will be read, for example, as input to a critical yes/no question. You can use the intrflush() function to have keyboard input flushed when the user presses an interrupt key. See interflush().

[Set04]

flushinp();

The basic origins of photovariation of LCST are the photomodulation of hydrophobic binding and Van der Waals interactions. To enhance the effect (at xed degree of modi cation with azo, i.e., to achieving larger a values) it is possible to optimize the effect of isomerization on the chromophore chromophore (attractive) interaction and the chromophore-water (repulsive) interaction. The energy of hydrophobic association is certainly dif cult to estimate, but should depend mainly on the number of carbon atoms that can be transferred in apolar microdomains. If the azos are fully accessible in the modi ed polymers (e.g., exible chains, long spacers), the isomerization does not markedly affect the hydrophobic binding. In contrast, the E Z conversion modi es the dipole interactions to an extent that should vary in proportion to the dipole moments of E and Z forms (irrespective of polymer composition), making thus the aUV atrans coef cient in Equation 7.1 proportional to the dipole variation. We remark that almost optimal photoswitches of dipolar interaction have been reached in the published investigations, because the azobenzenes used were essentially apolar under their trans form and polar under their cis form. Improvements are therefore not obvious, and shall be devised on new basis, for instance, using additional enthalpic contributions to the intrachain interaction.

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