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For example, it has been postulated that the stacking structure of the LbL lms of the PDADMAC/(Congo Red) produces a con ned geometry to enhance the stability of the Z-isomer of Congo Red (He et al, 2000) It was shown that covalent bonding of chromophores to the polymer matrix limits the degree of freedom and thus stabilizes their light- and electrical eld induced orientation (Marino et al, 2000; Boilot et al, 1998) But the main effect achieved by covalent bonding the chromophores to the polymer matrix was the suppression of their aggregation and thus the higher dye loading, which was impossible in guest host materials Understandably, high concentrations of chromophores are desirable for any optical effect in these materials, including nonlinearity, anisotropy, and SRG Concentration dependence of SRG formation has been investigated on a series of functionalized polymers (Borger et al, 2005).



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if( r == ERR)

while( function() == ERR)

Organization for the Advancement of Structured Information Standards (OASIS): UDDI Version 3.0, October 2002 http://www.uddi.org/specification.html





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The higher the azobenzene concentration, the more ef cient the grating formation, unless it becomes suppressed by increasing aggregation of chromophores, which is not excluded even in covalently bound systems The prevention of dye aggregation is one of the key challenges of functionalized polymer systems Intermolecular interactions have been demonstrated to be convenient means to reduce the tendency of the molecules to aggregate (Priimagi et al, 2007, 2006, 2005) Using ionic interaction between an ionic dye and a polyelectrolyte, a 1:1 molar ratio of dye molecules can be attached to the polymer simply by mixing the constituents (Priimagi et al, 2006; Stumpe et al, 2006a) Ionic complexes of polyelectrolytes and charged azobenzenes have optical response of the azobenzene, although in uenced by the polymer matrix, as discussed earlier The repeated E Z isomerization is considered as a primer condition for the light-induced mass transport.

The value of ERR is set in NCURSES.H to -1.

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Peculiar to the latter is the fact that the process is not more a local light-induced event but implies a translational motion of chromophores (Fig 21) Moreover, the mass is transported only if the chromophores involve the passive polymer chains in their translation This explains the high ef ciency of SRG formation in functionalized polymers (Natansohn and Rochon, 2002; Viswanathan et al, 1999), why the covalent bonding has been considered as a necessary condition for the effective lightinduced mass transport (Oliveira et al, 2005; Zucolotto et al, 2003; Fiorini et al, 2000; Viswanathan et al, 1999;), and why the extremely effective SRG formation in the materials with ionic-bounded azobenzene (Kulikovska et al, 2007; Stumpe.

Not every function returns ERR on failure. Some don t return anything; others may return NULL or have some other factor used to determine the function s failure. ERR s counterpart is the OK constant. See OK.

[Oas03a]

if( touchwin(menu) == ERR)

et al, 2006a) was rather unexpected It is also why in the latter case the process is determined not only by chromophore itself but to a large extent also by the intermolecular interactions and by the passive matrix (Kulikovska et al, 2007, 2008a) Because of its nonlocal nature, the light-driven diffusion presents a very sensible and elegant tool to study the intermolecular interactions The applicability of the supramolecular approach for SRG recording has been demonstrated by combination of different charged azobenzene derivatives with different polyelectrolytes Such azobenzene derivatives as Brilliant Yellow, Alizarin Yellow GG, and Methyl Red, all commercially available, have been used as active components The chemical structures of the compounds are shown in Fig 27 Note that the absorption may be tuned by a proper selection of the dye component that can match speci c applications where given laser wavelengths must be used.

nodelay(stdscr,TRUE); while( getch() == ERR)

Organization for the Advancement of Structured Information Standards (OASIS): Security Assertion Markup Language (SAML), Version 1.1, September 2003 http://www.oasis-open.org/committees/security/

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