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It is clear from Fig. 7.2 and Table 7.1, that the samples are made lightresponsive in the temperature range comprised between the LCSTs of the cis and trans forms, respectively. This range might be optimized by proper choice of chemical structures (nature of substituents on azobenzene, nature and length of spacer between the azo and polymer backbone), but except for hydroxypropyl, methyl-cellulose (HPMC), the present data re ect a contribution of azo side groups essentially of the same order of magnitude. A typical value of aUV atrans is, up to now, of 21C711C/mol% azo (except for the HMPC data that reach 6 71C/ mol%). Recalling the constraint of using chains with less than a few mol% azo (cf. introduction), this simple estimate shows that a degree of integration of 1 mol% in chains would impart the system with a typical phototriggered LCST-shift of 21C, only compatible with applications in highly controlled temperature conditions.



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TAB L E 7 .1 . Indices of LCST Shifts with Integration Level of Azobenzene Side Groups and Upon Photo-isomerisation

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effects of photoisomerization into the cis state, thermal relaxation back to the trans state, and possibly cis reconversion upon light absorption The steady-state composition is unique to each system, as it depends on the quantum yields for the two processes (Ftrans and Fcis) and the thermal relaxation rate constant The composition also depends on irradiation intensity, wavelength, temperature, and the matrix (gas phase, solution, liquid crystal, sol gel, monolayer, polymer matrix, etc) Azos are photochromic (their color changes on illumination), since the effective absorption spectrum (a combination of the trans and cis spectra) changes with light intensity Thus absorption spectroscopy can be conveniently used to measure the cis fraction in the steady state (Rau et al, 1990; Fischer, 1967), and the subsequent thermal relaxation to an all-trans state (Beltrame et al, 1993; Hair et al, 1990; Eisenbach, 1980a; Gabor and Fischer, 1971).

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Nuclear magnetic resonance (NMR) spectroscopy can also be used (Magennis et al, 2005) Under moderate irradiation, the composition of the photostationary state is predominantly cis for azobenzenes, mixed for aminoazobenzenes, and predominantly trans for pseudo-stilbenes In the dark, the cis fraction is below most detection limits, and the sample can be considered to be in an all-trans state Isomerization is induced by irradiating with a wavelength within the azo s absorption spectrum, preferably close to lmax Modern experiments typically use laser excitation with polarization control, delivering on the order of 1 100 mW cm 2 of power to the sample Various lasers cover the spectral range of interest, from the UV (Ar+ line at 350 nm) through blue (Ar+ at 488 nm), green (Ar+ at 514 nm, YAG at 532 nm, HeNe at 545 nm), and into the red (HeNe at 633 nm, GaAs at 675 nm).

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