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The expansion has both a reversible and irreversible component, suggesting both elastic deformation and viscoelastic ow play a role in azo mass transport Contraction is observed in LC materials, whereas expansion observed in amorphous polymers is consistent with other investigations For instance, for thin lms oating on a water surface, a contraction in the direction of polarized light was seen in liquid crystal materials, whereas an expansion was observed for amorphous samples (Bublitz et al, 2000) Experiment combining neutron re ectometry and AFM identi ed both photoexpansion and photocontraction in a single material (Yager and Barrett, 2006b; Yager et al, 2006b) In particular, photoexpansion was observed at low temperatures, whereas photocontraction was observed at higher temperature, with a distinct crossover temperature (at B501C for pdr1a) This suggests that material motion involves two competing mechanisms: one that causes material expansion (eg.



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Pair Pair Pair Pair Pair 1: 2: 3: 4: 5: White foreground, Blue background. Black foreground, Red background. Yellow foreground, Red background. Blue foreground, Green background. Cyan foreground, Magenta background.

PAIR_NUMBER()

, the internal pressure from the free volume required for azo isomerization) and one that causes material contraction (eg, dipole pairing and crystallization of azo groups) At low temperatures.

PAIR_NUMBER(attr)





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Lifecycle Management Patterns The next diagram shows how lease expiration is handled. Leases are handed out on a per-client and remote object basis. Several potential approaches exist: Check lease validity whenever a request arrives. If the lease has expired in the mean time, the remote object is deactivated and the lease is deleted. An error is reported to the client. Have a background thread check all leases in turn, continuously, and delete those remote objects and leases that are no longer valid. Register a callback function for the point in time at which a remote object s lease is expected to expire. The callback function can then check whether the remote object can be deactivated. This approach is often used in event-based systems. The first approach seems simplest, but has a serious drawback: if a client does not invoke the remote object regularly, the system will not notice the lease expiration, and the remote object will not be deactivated. As a consequence, one or other of the second two approaches is necessary in all cases. However, it can still be useful to combine onrequest-checks with a background thread solution, as this avoids situations in which the lease has expired but the background thread has not yet run.

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attr is the value produced by the COLOR_PAIR(n) attribute. It s the value used internally when NCurses builds attribute information to be stored on the screen in the chtype variable. (See Appendix C.)

Irradiation with light produces molecular changes in azobenzenes, and under appropriate conditions, these changes can translate into larger scale motions and even modulation of material properties. Following Natansohn and Rochon (2002), we will describe motions roughly in order of increasing size scale. However, since the motion on any size scale invariably affects (and is affected by)

The value returned by PAIR_NUMBER() is an int is equal to whichever color pair number has been used to format the text and background colors. Its range is between 0 and the value of COLOR_PAIRS, minus 1.

other scales, clear divisions are not possible. In all cases, some of the implicated applications, photoswitching, and photomodulations will be outlined.

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In reality, COLOR_PAIR(n) is simply a cluster of bits used in the chtype value to define how a character in an NCurses window is formatted. The PAIR_NUMBER() pseudo function simply extracts the COLOR_PAIR(n) value, n itself, from that chtype value. This is why it s often written that PAIR_NUMBER() is the opposite of the COLOR_PAIR(n) function.

n = PAIR_NUMBER(a)

The fundamental molecular photomotion in azobenzenes is the geometrical change that occurs on absorption of light In cis-azobenzene, the phenyl rings are twisted at 901 relative to the C N=N C plane (Naito et al, 1991; Uznanski et al, 1991) Isomerization reduces the distance between the 4 and 4u positions from 099 nm in the trans state to 055 nm in the cis state (Brown, 1966; Hampson and Robertson, 1941; de Lange et al, 1939) This geometric change increases the dipole moment: whereas the trans form has no dipole moment, the cis form has a dipole moment of 31 D (Hartley, 1937) The free volume requirement of the cis is larger than that of the trans (Naito et al.

The value of variable a is equal to the value of a specific COLOR_PAIR(n). The value returned in variable n will be the same as a from COLOR_PAIR(a).

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