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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 #include <ncurses.h> int main(void) { char buffer[81]; initscr(); addstr( Type on the keyboard whilst I wait...\n ); refresh(); napms(5000); /* 5 seconds */ addstr( Here is what you typed:\n ); flushinp(); getnstr(buffer,80); refresh(); endwin();



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Typical attempts at enhancing the impact of E Z conversion on intrachain and monomer-solvent interactions use solution of CDs in water. CDs form host guest inclusion complexes with azobenzene derivatives (Zheng et al., 2002; Sanchez and deRossi, 1996; Yang et al., 1996; Suzuki et al., 1991). The association with CDs of azobenzene-containing chains adds further degrees of complexity (interaction between CDs and nonazo monomers can be attractive or repulsive) to the intrachain interactions. The association of CDs with the chain may depend on the E Z isomerisation. It was found that aCD and bCDs are best suited than larger CDs to discriminate the E and Z isomers of azobenzene. Naturally, the association of CD modi es the enthalpy of chain folding and collapsing, by masking the hydrophobes in CD cavities, and adding CD-monomers contacts and steric hampering to conformational freedom. All these effects contribute to chain swelling or collapse. The common interpretation of photoresponses in the presence of CDs invokes that the trans isomer associates tightly into the CD cavities, whereas the cis isomer does not bind (Zheng et al., 2004; RodriguezCabello et al., 2002; Ueno et al., 2002). Measurements by NMR and circular dichroism validate this point in some systems containing aCD (Tomatsu et al., 2006; Zheng et al., 2005). In general, things are less obvious, and CDs (especially bCD) may partially dissociate upon transconversion to the cis form, or bind to both the E and Z forms of azobenzene, with a different geometries and stoichiometries (Fig. 7.3a; Inoue et al., 2007; Pouliquen et al., 2007; Tomatsu et al., 2006). Both phenomena make nevertheless the azo-modi ed chains more hydrophilic in presence of CDs (upper shift of LCSTs). The dark-adapted (trans) form is even





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K. E. Sorensen: Sessions, Proceedings of the 7th European Conference on Pattern Languages of Programs (EuroPLoP 2002), Irsee, Germany, July 2002 D. C. Schmidt, M. Stal, H. Rohnert, F. Buschmann: Pattern-Oriented Software Architecture Patterns for Concurrent and Networked Objects, John Wiley & Sons, 2000 M. Stal: The Activator Pattern, 2000 http://www.stal.de/articles.html

19 20

return 0; }

100 Transmittance (%) 80 60 40 20 0 10

Sample output:

[SSRB00]

Here is what you typed:

40 50 Temperature ( C) (b)

7, intrflush(), quiflush(), typeahead()

[Sta00]

Figure 7.3. Effect of CD host guest interaction on azobenzene-modi ed polymers. (a) Drawing of the equilibrium between bound and unbound CDs. With the change of geometry under the cis form approaching the CD toward the backbone, Ktrans may be higher than Kcis. (b) Experimental variation of turbidity and shift of LCST measured in mixtures of hydroxypropyl methylcellulose in the presence or absence of aCD as quoted in the gure. Source: Reprinted with permission from Zheng et al., 2004.

getbegyx()

The getbegyx() function returns the upper-left coordinates, the top-left corner, of the named window.

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more hydrophilic than the cis one, presumably because of the deeper penetration of the E-form inside the CD cavity. Consequently, the coef cient aUV atrans in Equation 7.1 can become negative. In such mixed systems, the rst stage of ampli cation is achieved by recognition of azobenzene s isomers at the molecular scale. The second ampli cation stage is brought by chain collapsing in poor solvent. The development of new photocomplexing agents coupled with chain collapsing could certainly help design systems with a large temperature range of photoresponsiveness.

void getbegyx(WINDOW *win, int y, int x);

[Sta03]

win refers to a specific window. It s a WINDOW variable representing a window or subwindow. (Pads do not have an origin coordinate.) y and x are int variables that will hold the starting row and column number of the win window. Row 0, column 0 represents the upper-left corner of the screen. Note that these are not pointer variables.

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