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the absorbance of the p p* transition band at 360 nm decreases and the absorbance of the n p* transition band at 450 nm increases gradually. The relative absorbance A(t) is de ned as A/Aorigin, where Aorigin and A are the absorbance at 360 nm before the light irradiation and after the irradiation for different time periods. The gure shows the relative absorbance of the solutions and suspensions as a function of the UV light irradiation time and the tting curves of the rstorder exponential decay function. The suspensions have an initial polymer concentration of 0.5 mg/mL and different water contents. When the water content is in the range 23.1% 33.3% (vol%), the trans-to-cis photoisomerization kinetics is similar for the systems. As CWC is 26.8% (vol%) obtained from light-scattering measurement, the observation indicates that the isomerization rate does not change signi cantly just above CWC. When the water content further increases to 40% 50% (vol%), the photoisomerization rate starts to decrease obviously. When the water content is even higher (80%, vol%), the isomerization rate decreases drastically, but it is still faster than that of the spheres obtained from the quenching and dialysis procedure. The trans-to-cis isomerization degree at the photostationary state indicates a similar tendency (Fig. 5.6). The isomerization degree at the photostationary state is estimated from (Victor and Torkelson, 1987) 5:1 isomerization degree 1:05 1 As =Aorigin where As is the 360 nm absorbance measured at the photostationary state. When the water content increases in range from 25% to 37.5% (vol%), the isomerization degree is 80% (vol%) and almost keeps constant with the water content increase.



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int setscrreg(int top, int bot); int wsetscrreg(WINDOW *win, int top, int bot);

2c) activate() 2f) deactivate()

top is an int value indicating the top row for the scrolling region. Values range from 0 for the top row, to the value of bot minus 1. bot is in int value indicating the bottom row of the scrolling region. Values range from top+1 to the bottom of the window. Refer to the w entry elsewhere in this appendix for information on the win argument.

0.85 0.80 Isomerization degree 0.75 0.70 0.65 0.60 0.55 0.50 20 30 40 50 60 Water content (v%) 70 80

OK on success, ERR on failure. The function fails when top is greater than or equal to bot, or when bot is greater than the bottom of the window.

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This function works only after scrolling has been enabled for the window via the scrollok() function. See scrollok(). Unless setscrreg() is used, the top and bottom rows of the window define the scrolling region. The bottom row of the window can be returned using w->_maxy, where w is the window s WINDOW variable name. Text can still be written to the window below the scrolling region, specifically by using the various mv-prefix text output functions.

Figure 5.6. The relationship between the isomerization degree at the photostationary state and the water content. The suspension was prepared from a THF solution with the initial polymer concentration of 0.5 mg/mL. Source: From Li et al., 2006a.

setscrreg(5,stdscr->_maxy);

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When the water content further increases, the isomerization degree starts to decrease. When the water content increases from 37.5% to 80% (vol%), the isomerization degree decreases from 80% to ca. 55%. For the spheres in the water suspension, obtained by quenching with an excessive amount of water and dialysis, the isomerization degree decreases to even 33%. The preceding results obtained from the UV-vis spectroscopic measurements indicate that in the water addition process, the aggregates undergo a collapse process after the water content is above 40% (vol%). In the water addition process, the water-adding rate shows a critical in uence on the colloid formation. The slow addition rate is necessary to obtain uniform colloids. In a broad water-dropping rate, the sizes of the colloids obtained at the nal stage are almost the same. However, when the water-dropping rate is extremely slow, the colloid size will abruptly increase as the dropping rate further decreases and even the aggregates will precipitate from the suspension.

wsetscrreg(options,2,opbot);

A LIFECYCLE MANAGER is typically created by the server application during start-up, and is registered with the distributed object middleware s INVOKER. Before an invocation is dispatched, the INVOKER informs the lifecycle manager. If the servant is not active, the LIFECYCLE MANAGER activates it. The INVOKER dispatches the invocation. After the invocation returns, the LIFECYCLE MANAGER is informed again and can deactivate the servant if required.

Here, the statement creates a scrolling region in the window options, from line 2 (the third line) of the window through the value represented by opbot.

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