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shells because they are often not full. If we add energy to an atom, an electron will jump from an outer shell to an even higher energy shell. Similarly, that electron will drop back down to its regular level when it loses its energy. The normal outer shell of an atom is the valence and the energy level of that shell is its valence band. The next band out is the conduction band. When an electron is in the conduction band, it is very loosely bound to the atom and can be easily pushed into a neighboring atom s conduction band. The amount of energy needed to jump an electron from the valence to the conduction band is the band gap (Fig. 12-2). Conductors have a very small band gap so that the energy available at room temperature kicks a bunch of the conductor s electrons into the conduction band. A solid made up of these atoms has a loose sea of electrons that is easily shifted around. An insulator has a large band gap. It takes a lot of energy to kick an electron out of its valence band and into the loosely held conduction band. Semiconductors have a medium-sized band gap and are mostly insulators.



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Summary of the minimum shear modulus [28]

Plane {100} {110} {111}

Silicon (Si, element 14) is a semiconductor. At room temperature, silicon conducts a little bit. The energy available during normal operating conditions kicks some of its valence electrons into the conduction band. Not many, maybe one in a billion, but enough to create a perceptible current. The colder the silicon is, the less it will conduct because the electrons lose their energy and fall back into the valence band. A simple component, the thermistor, takes advantage of this feature, changing its resistance based on the temperature. The conduction behavior of a silicon semiconductor can be adjusted by alloying it with small amounts of impurities, or dopants.





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Brookes [29] has examined the anisotropy in diamond hardness on the {100} planes It appears that in the <100> directions, the maximum hardness is obtained and in the <110> directions, the minimal hardness This is contrary to the opinion that the difficult polishing directions are those of maximum hardness The properties of diamond are summarized in Table 27

The properties of diamond on the {100} planes [30]

Imagine, if you will, a tetrahedral lattice of silicon where each atom is bound to four other silicon atoms If this lattice were squashed at and drawn in a schematic form, it might look like Fig 12-3 Since only the outer shell interacts with the neighboring atoms, we simplify the atom and draw only this outer shell and its four electrons Silicon creates covalent bonds with four of its neighbors, meaning they share electrons in the valance shell The valence shell in silicon has four electrons but has room for four more It is these empty slots in the shell that are lled by electrons from neighboring atoms This creates a tight bond between the atoms and keeps the electrons rmly in place.

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Friction coefficient, (obtained from cast iron wheel at a speed of 64 m/sec) 020 018 014

Hardness (N/mm2)

What if you added some phosphorus (P, element 15) to the silicon Phosphorus has ve electrons in its valence shell, but will still form covalent bonds with silicon Figure 12-4 shows this, though it is hard to see With ve electrons but only four of them tied in a covalent bond, there is an unbound electron This electron is free to jump into the conduction band, giving this alloy more free electrons A semiconductor with these free electrons is an n-type semiconductor Note that the material still has a neutral charge, the same way that copper has a neutral charge There are simply more loose electrons available to move when a voltage di erential is created What if you added some boron (B, element 5) to the mix Boron has only three electrons in its valence shell, but will still form covalent bonds with silicon Figure 12-5 shows this.

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In this case, there are a number of covalent bonding positions that are not lled by the boron These holes are places where a free electron can get stuck This type of alloy is a p-type.

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