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The lm morphology of the nominally amorphous lm was rougher than that for the separate Bi2Se3 and Sb2Se3 lms The optical band gap of a lm grown using precursor solutions with Bi:Sb concentration ratio 1 : 1 was 157 eV, and the resistivity was 104 cm111 114 83211 In2S3 Indium sul de lms have been grown using solutions of indium(III) chloride and indium(III) sulfate complexed with triethanolamine and hydrazine hydrate115 117 The lms grown from the indium chloride precursor were amorphous or nanocrystalline (ie, cubic structure), but those grown from complexed indium precursor were rhombohedral, possibly because of the complexation Annealing the lms grown from indium chloride at 400 C improved the crystallinity of the lms, and a tetragonal In2S3 phase was detected, along with secondary indium-rich phases like InS and In6S7117 The band gap varied from 23 to 2.



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7 eV, and it was reduced to 14 15 eV after annealing at 400 C115 117 83212 SnS2 Weakly crystalline SnS2 lms have been grown from tin(II) chloride and sodium sul de precursors EDX analysis gave a Sn/S ratio of 1/202 The surface roughness of a 290-nm-thick lm was 32 nm The band gap was 222 eV, and the photoluminescence spectra, using a 325 nm excitation source, showed peaks at 549 nm and 700 nm118 83213 MoS2 SILAR-grown molybdenum sul de and zirconium oxide lms have been tested as coatings for MEMS silicon test devices The MoS2 and ZrO2 coatings decreased the coef cient of friction relative to that of uncoated devices The SILAR-grown coatings showed high wear120 83214 CuInS2, CuInSe2.

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CuInS2 (CIS), lms have been grown from mixed copper(II) chloride, indium(III) chloride cation precursor, and sodium sul de anion precursor solutions121,122 XPS and XRD analyses revealed that, when the copper/indium concentration ratio in the solution was 125, a stoichiometric CIS lm could be grown The electrical parameters obtained with different copper/indium concentration ratios have been investigated121.

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phase detection imaging and Young s modulus microscopy Fresenius J Anal Chem 361:613 617 Lokhande, C D; Pathan, H M; Giersig, M; Tributsch, H 2002 Preparation of Znx(O,S)y thin lms using modi ed chemical bath deposition method Appl Surf Sci 187:101 107 Battaglia, D; Blackman, B; Peng, X 2005 Coupled and decoupled dual quantum systems in one semiconductor nanocrystal J Amer Chem Soc 127:10889 10897 Kale, R B; Lokhande, C D 2004 Room temperature deposition of ZnSe thin lms by successive ionic layer adsorption and reaction (SILAR) method Mater Res Bull 39:1829 1839 Kale, S S; Mane, R S; Pathan, H M; Shaikh, A V; Joo, O-S; Han, S-H 2007 Preparation and characterization of ZnTe thin lms by SILAR method Appl Surf Sci 253:4335 4337 Tamulevicius, S; Valkonen, M P; Laukaitis, G; Lindroos, S.

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