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When a guard g appears in the de nition f of a color function, [g]f designates the tuple f guarded by g. This guard modi es the value of f in the following manner. DEFINITION 7.17 (Guarded color function). Let f be a tuple of elementary functions and g a guard. The guarded tuple [g]f is de ned by [g]f (c) = if g(c) then f (c) else 0 So, a guarded color function is a sum of guarded tuples. The two models in Figure 7.13 illustrate the difference between a guarded transition and a guarded function. In the left hand model the transition t is only enabled for the values < c, c > of C C, verifying c = 0 4. In the right hand model, t is enabled only for a couple of values < c, c > provided that on the one hand there is at least one token of color c in P 1, and on the other hand, either c = 0 or there is at least one token of color c in P 2: therefore t may be enabled for values < c, 0 >. If t is red for < c, c > with c = 0, a token of color c is removed from place P 1, a token of color c is removed from place P 2, and a token of color < c, c > is produced in Q. Otherwise, if t is red for a value < c, 0 > then only one token c is removed from P 1 (no precondition on P 2) and a token of color < c, 0 > is produced in Q.

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All are leadsiliceous glazes, slightly enriched in K2 O and CaO, opaci ed by tin oxide and coloured with different metallic oxides: cobalt for blue, manganese for purple, lead antimoniate for yellow, copper for green The microstructure of the glazes (SEM images) is quite typical: a homogeneous glassy matrix ( 150 m thick for both pairs) with unmelted quartz grains or feldspar, heterogeneous re-partition of tin oxides crystals and bubbles The glazes are very similar for the two angels of the same pair and their compositions are compatible with the Renaissance recipes published in old ceramics treatises If the blue glazes are considered, the two pairs differ sharply (Figure 7314) Cobalt is usually associated with other metallic elements that re ect the origin of the ores as well as the different methods of puri cation of the metal.

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Figure 2.13. (a) Thermodynamic driving force ( Gv) associated with the phase transformation from the amorphous to the crystalline state and (b) classic picture of the energy barrier associated with nucleation resulting from the balance of the surface energy and volume free energy terms. [(a) Adapted from Ref. 64: C. J. Brinker and G. W. Scherer, Relationships between the sol-to-gel and gel-to-glass conversions, In Ultrastructure Processing of Ceramics, Glasses, and Composites, edited by L. L. Hench, D. R. Ulrich, pp. 43 59, 1984. Reprinted with permission of John Wiley & Sons, Inc.]

Cobalt is associated with Ni, Cu, Fe for the pair RF1533-RF1534, whereas appreciable amounts of As2 O3 are measured in the blue glazes of the other pair Studies aiming at tracing the ancient commercial routes of cobalt in Europe37,45,46 suggest a compositional change of raw material at the boundary of fteenth sixteenth century, with increased amounts of As, probably due to a different re nement process of the mineral ores The two pairs of angels seem to t in this scheme: the Della Robbia bottega was founded around 1440 while the.