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Rating 3.7 At large separations r1 (Figure 312), interactions between lled orbitals (a, b, c) will be negligible The largest interactions will be between the virtual orbitals (h), but since there are no electrons, there are no energetic consequences Notice that addition of an electron to the pair (or larger assembly) of neutral molecules would lead to maximum stabilization of the electron if interaction h is maximized The solvated electron in liquid ammonia is an example of such a system An electron solvated by two water molecules has been detected in the gas phase The system has been studied theoretically and found to adopt a geometry expected on the basis of maximizing LUMO LUMO interactions ([70]; see also reference 71 for references to other studies of electrons attached to small clusters) At intermediate separations r2 (Figure 3. pdf editing software for windows 10 free Win PDF Editor : Edit PDF Content, Remove PDF Text - Downloada
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