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As described in Sec. 5.3, DC polarography is used to study the complex formation of metal ions. If a metal ion Mn+ reacts with ligand L to form a complex MLn+, p we can get the value of p and the formation constant K by measuring the halfwave potential for the reduction of the metal ion as a function of the ligand concentration. When a successive complex formation (Mn+ 3 MLn+ 3 MLn+ 3 3 2 2 2 2 2 MLn+) occurs, we can determine the successive formation constants. In aprotic p solvents, the reduction of organic compounds (Q) in the presence of metal ions (M+) is sometimes used to get the formation constants of ion-pairs, Q M+ (see 10) ). In some cases, the effect of metal ions on the voltammetric oxidation of organic ligands gives information on metal complexation; thus, the anodic oxidation of cryptands at a rotating gold-disk electrode has been used to get the stability of metal cryptates [28]. However, recent interest in polarography and voltammetry of metal complexes in non-aqueous solutions has mainly focused on the so-called organometallic complexes. Many organometallic complexes, which are insoluble in water, are soluble in non-aqueous solvents. In particular, in aprotic solvents, many of the reaction products and intermediates, which are unstable in water and other protic solvents, are stabilized to a considerable extent. Thus, in appropriate aprotic solvents, we can study the elementary processes for the reduction and/or oxidation of organometallic complexes. By studying these processes, we can obtain useful information about the redox properties of the complexes, including their electronic properties and the sites of electronic changes. Cyclic voltammetry, which is most useful in such studies, is now popular in the field of coordination chemistry. The following are some examples of the electrode reactions of organometallic complexes.



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Fluvial processes and the establishment of bottomland trees Geomorphology 14:327 339 Scott, M L, P B Shafroth, and G T Auble 1999 Responses of riparian cottonwoods to alluvial water table declines Environmental Management 23:347 358 Shafroth, P B, J M Friedman, and L S Ischinger 1995 Effects of salinity on establishment of Populus fremontii (cottonwood) and Tamarix ramosissima (saltcedar) in southwestern United States Great Basin Naturalist 55:58 65 Shafroth, P B, J C Stromberg, and D T Patten In press Riparian vegetation response to altered disturbance and stress regimes Ecological Applications Shafroth, P B, G T Auble, J C Stromberg, and D T Patten 1998 Establishment of woody riparian vegetation in relation to annual patterns of stream ow, Bill Williams River, Arizona Wetlands 18:577 590 Sher, A A, D L Marshall, and S A Gilbert 2000.





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Competition between native Populus deltoides and invasive Tamarix ramosissima and the implications for reestablishing ooding disturbance Conservation Biology 14:1744 1754 Shields, F D, A Simon, and L J Steffen 2000 Reservoir effects on downstream channel migration Environmental Conservation 27:54 66 Smith, S D, D A Devitt, A Sala, J R Cleverly, and D E Busch 1998 Water relations of riparian plants from warm desert regions Wetlands 18:687 695 Springer, A E, J M Wright, P B Shafroth, J C Stromberg, and D T Patten 1999 Coupling ground-water and riparian vegetation models to simulate riparian vegetation changes due to a reservoir release Water Resources Research 35:3621 3630 Stanford, J A, J V Ward, W J Liss, C A Frissell, R N Williams, J A Lichatowich, and C C Coutant 1996 A general protocol for restoration of regulated rivers Regulated Rivers: Research and Management 12:391 413 Stein, B.

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southeastern United States have a high level of tree mortality over time (Penfound, 1949; Eggler and Moore, 1961; Harms et al., 1980; Conner and Day, 1988, 1992; Heitmeyer et al., 1989; Osment-DeLoach and Moore, 1996). The length of time species can be ooded above the root crown and not suffer mortality varies widely between species, but most trees die if permanently ooded above the root collar for one to six years (Table 7-10) (Yeager, 1949). Acer negundo survived for 1460 days with ooding above the root crown, but Gleditsia aquatica died earlier (Yeager, 1949). All species eventually died in a mixed baldcypress swamp behind the Rodman Dam along the Oklawaha River, Florida, in water depths exceeding 1.3 m; however, many trees were crushed before the impoundment was built. As the depth of water increased in the impoundment, the relative amount of senescent root tissue increased as the amount of starch in the living root tissues decreased (Harms et al., 1980). Some species can recover if drawdown is reestablished; Taxodium distichum individuals that have been impounded for one (but not ve) years recover rapidly (Duever and McCollom, 1986). In Lake Chicot four years after the construction of a dam, although most of the Taxodium distichum and Planera aquatica were still alive in 0.6 to 3.0 m of water (97 and 83 percent, respectively), only 34 percent of the Nyssa aquatica were still alive (Penfound, 1949).

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A, L S Kutner, and J S Adams 2000 Precious Heritage: The Status of Biodiversity in the United States Oxford University Press, Oxford, UK..

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