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However, introducing the sample in a liquid matrix allows continuous replenishment of sample ions from the matrix surface Moreover, in the gas phase the matrix behaves in a similar manner to the reagent gas in CI shown in Figure 46, generating quasimolecular ions (either protonated (M + H) cations or deprotonated (M H) anions) from uncharged molecules of the sample in the gas phase In FAB, the matrix itself generates characteristic ions which are called matrix cluster ions which are useful in calibration of spectra A limitation of FAB arises from the fact that there seems to be a signi cant difference in ionization ef ciency between molecules that exist on the surface of the liquid matrix and those which are buried inside it (ie between sample components of differing hydrophobicities and surface activities).



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Molecules of the former type are much more readily ionized than those of the latter This is called selective desorption or suppression effect and it complicates analysis of FAB/MS spectra since the precise composition of the sample may not be known prior to the analysis Suppression effects are also a problem with other ionization methods and can be avoided by separating the sample before MS by some other high-resolution technique such as HPLC ( 2; Section 431) or electrophoresis ( 5; Section 433)..

The tolerable intake values for DEHP are outlined in the International Organization for Standardization ISO/DIS 10993-17 standard, Method for the Establishment of Allowable Limits for Leachable Substances.

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This chapter is concerned with organising your business to maximise profitability. It will enable y o u to create and develop profitable e-commerce activities by helping you to understand the effect of the Internet on employees, markets, customers and business partners. Key issues covered include:

You also see the Workspaces toolbar when you open AutoCAD or AutoCAD LT for the first time. I explain workspaces in the next section. If you don t want to use this toolbar right away, you can close it until you need it.

2 0 (a)

Because of the structure of the statement, only one of the conditions needs to be met for the statement to evaluate to true. Notice that none of the employees in department 30 makes it to the result set. There is no way for them to evaluate to true. The following statement will see employees of department 30 in the result set, because some of them have commissions greater than 500.

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A moment ago, you saved a preset for creating new files. Tool presets work in much the same way. You can save a preset for this tool by clicking the Create New Preset button on the pop-up menu, as shown in Figure 6.2. However, with this brush, you don t need to do this. It s already one of the default presets.

Figure 10.7 DicomImages folder (left) is the storage space and the hierarchy of the subfolders according to the order of Patient ID (55555555), Modality (1.3.12.2 . . .) (right), Accession number_study date_study time (1.3.12.2 . . . 11/2/2007 1:31 PM), and an auto-number. The le names of the images are their image instance UIDs.

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Figure 4.24. Analyte-enrichment interface for GC/MS Sample enters interface from GC. Sample components diffuse more ef ciently across a dimethylsilicone membrane than the carrier gas. 10 30-fold enrichment of sample is achieved with this interface.

The run-time interface of a business component system is defined as follows : The run-time interface of a business component system is either the union of all system-external interfaces of its constituent business components or the interfaces of its gateway.

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