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The differences in the savings potential between case D and E are +15,000 tons/year of fuel oil in the lower borderline case and +44,000 tons/year of fuel oil in the upper borderline case, that is, differences are in the vague zone of these calculations (Fig. 13.31). The discussions about those differences during the last amendment to the German Packaging Ordinance had the character of religious wars. Looking at the real differences, especially in scenarios D and E, one may wonder whether always the right priorities have guided public discussion. This question is even more justi ed when relating the values calculated here to the present total emissions in Germany (Fig. 13.32).





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Until recently the NIR region was not considered particularly useful for the spectroscopy of organic compounds The combination and overtone bands of molecular vibrations occur in the relatively narrow region of 750 3000 nm compared to the fundamental bands occurring at 2800 50,000 nm This was considered as a drawback In addition it was observed that NIR bands severely overlapped, were dif cult to resolve, and, once resolved, dif cult to interpret If samples were not dried prior to NIR analysis, the changes in hydrogen bonding due to the effects of sample temperature, ionic strength, and analyte concentration could also complicate interpretation of frequently overlapping NIR spectral bands Changes in hydrogen bonding produce band shifts as well as attening or broadening of band shapes The overtone and combination molecular absorptions found within the NIR region are inherently much less intense than the fundamental IR absorptions.

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Thus, the changes in absorbance in the NIR region are quite small with respect to changes in concentration The relatively small extinction coef cients due to combination and overtone NIR bands severely restrict the allowable noise levels and stability of any NIR instrument that is used for quantitative work Sample presentation and the relatively straightforward re ectance measurement involved aspects which were not expected with traditional IR spectroscopy If analytical information is obtained with better resolution in the IR region, why should a chemist be interested in NIRS Numerous dif culties inherent in the use of qualitative NIRS led to its rejection by analytical chemists Karl Norris, an engineer at the US Department of Agriculture, demonstrated the potential value of the NIR region for quantitative work by making measurements of agricultural products in the 1960s.

Several techniques have been developed to rapidly identify additives in plastics as part of an overall plastics recycling operation. Some techniques such as Fourier transform infrared (FTIR) can combine resin identi cation with information of the presence or absence of additives such as ame retardants or talc llers [49, 62, 65]. The sliding spark technique developed at the University of Duisburg in Germany can identify a range of heavy metals along with the type of resin [68, 69]. A reliable and reasonably fast method to identify a broad range of metals, halogens, and other heteroatoms in plastics is X-ray uorescence spectroscopy [70]. X-ray uorescence (XRF), which is based on energy level changes of core electrons of atoms, can be used to detect most elements in plastics except for H, C, N, and O. Since these atoms are usually present in relatively large amounts as part of functional groups observable by other techniques (such as infrared spectroscopy), XRF is a complementary technique for the analysis of other elements. Many of these other elements are found in additives and can appear in plastics in concentrations from parts per million to near 50%. XRF has the ability to cover this entire range for many elements. Though often less quantitative than other techniques, XRF has several advantages such as operator ease of use, quick

The basic idea was to provide various research and production facilities with online NIR measurements of agricultural products NIRS has now become widespread in the chemical and pharmaceutical industry, with the publication of multiple practical applications and a massively increased presence in specialized journals 42210 Bene ts of NIRS.

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