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The orbital p4 , which is closest in energy to the carbene's p orbital, does not interact because of symmetry, and p5 interacts less strongly because the coe cients at the terminal positions of the hexatriene are H H smaller The larger HOMO sp n LUMO (p4 or p5 ) gap permits the ground state to be singlet 5 Use orbital interaction analysis to suggest a reason that tropylium cation C7 H is 7 such a stable cation This may be done in either of two ways: by considering the interaction of a simple carbocation with 1,3,5-hexatriene or the interaction of an allyl cation with butadiene, both held in the 7-membered planar ring geometry of tropylium In either case, attention must be paid to orbital symmetry 6 Use orbital interaction analysis to predict the structure of a complex between H2 O and :CH2 .



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The structure was determined by ab initio MO theory (Moreno, M; Lluch, J M; Oliva, A; Bertran, J, Can J Chem, 1987, 65, 2774 2778) 7 Methyl methoxy carbene, CH3 C OCH3 , was described recently (Sheridan, R S; Moss, R A; Wilk, B K; Shen, S; Wlostowski, M; Kesselmayer, M A; Subramanian, R; Kmiecik-Lawrynowicz, G; Krogh-Jespersen, K, J Am Chem Soc, 1988, 110, 7563 7564) as a remarkably selective nucleophile Explain why the carbene, CH3 C OCH3 , has a singlet ground state and determine the basis for its ``nucleophilicity'' 8 Benzyne is considered to be the intermediate in strong base-catalyzed nucleophilic aromatic substitution..





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If the sequence of elementary matrices above is encountered repetitively, as is the case, for instance, if they represent the components all the way around a circular accelerator, then we can use this matrix to enquire into the stability of transverse oscillations. For an oscillation to be stable, the quantity

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