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studied in Et4NClO4-acetonitrile (AN) [5, 6]. 3) In this method, the substance to be measured is generated in situ by controlled-potential electrolysis and its concentration at every moment is traced. Thus, the reactivity of an unstable substance (lifetime of * 100 ls) can be studied. Various other methods have been developed for studying rapid reactions, e.g. the pulse radiolysis and flash photolysis methods. Compared with such methods, the present method has a merit that the reactive substance can be generated at the best condition by the controlled-potential electrolysis. However, the cell in Fig. 9.2(b) has a disadvantage in that the concentration of the electrogenerated substance decreases with increasing distance from the OTE surface. Because of this, simulation of the reaction is very difficult, except for the first order (or pseudo-first-order) reactions. For more complicated reactions, it is desirable that the concentration of the electrogenerated species is kept uniform in the solution. With a thin-layer cell, a solution of uniform concentration can be obtained by complete electrolysis, but it takes * 30 s. Thus, the thin-layer cell is applicable only for slow reactions. For faster reactions, a column-type cell for rapid electrolysis is convenient. Okazaki et al. [7] constructed a stopped-flow optical absorption cell using one or two column-type cells (Fig. 9.4) and used it to study the dimerization of the radical cations (TPA +) of triphenylamine and the reactions of the radical cation (DPA +) of 9,10-diphenylanthracene with water and alcohols. Using the stopped-flow cell, reactions of substances with a half-life of * 1 s can be studied in solutions of uniform concentrations.



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mainly by the RC delay of the source resistance and load capacitance. For several values of interconnection widths, load voltage waveforms in the time range 0 50 ps are shown in Fig. 3.3.5 and the dependence of delay time on interconnection widths in the range 0.5 5 mm is shown in Fig. 3.3.6. Figure 3.3.6 shows that the delay time becomes a minimum when the interconnection widths are about 2 mm each. The increase in delay time for widths below about 2 mm is due to the increasing line resistance due to decreasing cross-sectional area whereas the increase in delay time for widths above about 2 mm is due to the increasing ground and coupling capacitances of the interconnection lines. For four different values of interconnection separation, load voltage waveforms in the range 0 50 ps are shown in Fig. 3.3.7 and the dependence of delay time on interconnection separations in the range 0.5 5 mm is shown in Fig. 3.3.8. Figure 3.3.8 shows that the delay time decreases as the separations are increased. This is because the coupling capacitances decrease as the distances between the neighboring interconnection lines are increased. Load voltage waveforms in the time range 0 500 ps for several values of interconnection metal resistivity are shown in Fig. 3.3.9 and the dependence of delay time on resistivities in the range 0.1 1,000 m cm is shown in Fig. 3.3.10. This gure shows that for resistivities above about 10 m cm the delay time increases signi cantly. It should be noted that, besides aluminum, WSi2 and poly-Si have also

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For large m, this sum approaches the desired integral. The suf cient statistics, n n i=1 y0i = 750 and i=1 y1i = 300, are constructed from the MLEs for 0 and 1 reported in Gross et al. (1971) based on 100 samples of kidney failure times. The Gibbs sampler had 1000 burn-in samples of 0 and 1 and 2000 samples from the posterior. Of these, every fth sample was taken to get m = 400 samples for the predictive density computation. Computing the autocorrelation function veri es that the samples are approximately uncorrelated. Figure 5.11 gives the Bayes predictive density of the time to total failure of the kidneys. The solid line in the gure is the predictive distribution, the posterior mean of fT (t| 0 , 1 ). The two dashed lines are the 5% and 95% pointwise prediction bounds. Figure 5.12 gives histograms of posterior samples with the MLE indicated by a vertical line.

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