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excess of the reagent that can cause overreaction. One reason for no overreaction is that there is no pathway in the reaction system for a consecutive reaction. That information can be very helpful on scale-up by eliminating one possible pathway for failure. For consecutive or parallel reactions, runs comparing very poor mixing and very good mixing can be helpful as a rst indication of sensitivity. Any differences, however small, should be cause for further study. In some cases, laboratory mixing, even when very poor, can be suf cient to prevent differences in product distribution. In these cases, pilot scale experiments may be required. A step-by-step recommended procedure for determining mixing sensitivity based on evaluation of the Damkoehler number may be found in Section 13-4. A laboratory reaction calorimeter can be very helpful in this type of experimentation. Use of this device is described in Section 17-2.6. Although there is no general rule or agreement on minimum size since there are critical dependency requirements of the speci c operation, 4 L is considered a minimum, recognizing the probable limited amounts of materials available or practical to obtain. Larger vessels can obviously provide better scale-up data. Smaller vessels (1 L) can also be adequate provided that they follow a standardized con guration. The reaction vessel should be cylindrical with a standard turbine, alloy or glass, agitation system, with baf es. A laboratory favorite, the round-bottomed ask, must be avoided since the results cannot be deemed reliable for mixing information and even for accurate assessment of selectivity for fast reactions.



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e q u a l s ( s y n c h ) ) c o r n = new SynchLinker (baseNanie, rnyId, n u m P r o c ) ; Chat c = new Chat(comm); for ( i n t i = 0 ; i < numProc; i++) i f ( i != myId) ( n e w L i s t e n e r T h r e a d ( i , c ) ) s t a r t ( ) ; B u f f e r e d R e a d e r d i n = new B u f f e r e d R e a d e r ( new I n p u t S t r e a i n R e a d e r ( S y s t e m .





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in ) ) ; while ( t r u e ) { S t r i n g cliatMsg = c g e t U s e r I n p u t ( d i n ) ; if ( chatMsg e q u a l s ( q u i t ) ) b r e a k ; Int Li nke d L i s t d e s t I d s = c getDest ( d i n ) ; i f ( a r g s [ 3 ] e q u a l s ( s y n c l i ) ) comm sendMsg( d e s t I d s .

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ClassAds: The ClassAd mechanism in Condor provides an extremely exible and expressive framework for matching resource requests (e.g. jobs) with resource offers (e.g. machines). ClassAds allow Condor to adopt to nearly any desired resource utilization policy and to adopt a planning approach when incorporating Grid resources. We will discuss this approach further in a section below. Job checkpoint and migration: With certain types of jobs, Condor can transparently record a checkpoint and subsequently resume the application from the checkpoint le. A periodic checkpoint provides a form of fault tolerance and safeguards the accumulated computation time of a job. A checkpoint also permits a job to migrate from

g e t E n t r y ( 0 ) , c h a t , c h a t l l l s g ) ; else c o r n nitilticast ( d e s t I d s , c h a t , chatMsg);.

Height [mm]

Both chromia-on-alumina and molybdena-on-alumina catalysts are active in hydroforming. Whereas the former gave better results at ambient hydrogen pressure, molybdena-on-alumina catalysts proved to exhibit much better performance at higher hydrogen pressures and were utilized in industrial practice. It is of industrial importance to note that hydroforming in fluid operation gave somewhat higher yields than did hydroforming in fixed-bed operation. 97 This occurred because the fluid operation gave less thermal cracking and operated at lower temperature and pressure. During World War II, hydroforming found ample use for the production of toluene and of components for aviation gasoline. After the war, hydroforming was used for the formation of high-octane gasoline for automobiles. The realization of the carcinogenic nature of toluene, however, greatly limits its role in gasoline and increasingly emphasizes the importance of isomerization and oxygenate additions in enhancing octane rating of gasoline. The most widely used blending component is MTBE (see, however, a discussion in Section 1.8.2 about the controversy of its use).

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