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As noted earlier, is the local energy dissipation rate, so eq (12-50 and 51) can be used for spatially dependent calculations For constant power number and relatively uniform energy dissipation in the circulation region of the tank, N3 D2 and the dependency on impeller speed and diameter can be established The terms in eq (12-50) are consistent with practice and our discussion in Section 12-313 The coalescence frequency (v, v ) is independent of the volume fraction of dispersed phase The coalescence rate can be obtained from the coalescence frequency by accounting for the number of drops of size v and v This is best demonstrated by reference to the population balance equations discussed in Section 12-4 Although dif cult to apply in practice, models for coalescence rate provide an appreciation for the physical phenomena that govern coalescence.

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They also provide an appreciation for why it is dif cult to interpret stirred tank data or even to de ne the appropriate experiment For instance, it can be clearly seen from eq (12-49) to (12-51) that the collision frequency increases with , whereas the coalescence ef ciency decreases with For constant phase fraction, the number of drops also increases with The models for coalescence of equal-sized drops are quite useful to guide the interpretation of data that elucidate the time evolution of both mean diameter and drop size distribution during coalescence To this end, Calabrese et al (1993) extended the work of Coulaloglou and Tavlarides (1977) to include turbulent stirred tank models for rigid spheres and deformable drops with immobile and partially mobile interfaces The later model accounts for the role of drop viscosity.

Listing 11-5: cvslib.py (Part 5 of 6)

In practice, models for unequal-sized drops are even more dif cult to apply, but they do suggest that rates are size dependent They are useful in the application of the population balance models discussed in Section 12-4 Numerous authors have developed models for coalescence frequency These include the models of Muralidhar and Ramkrishna (1986), Das et al (1987), Muralidhar et al (1988), Tsouris and Tavlarides (1994), and Wright and Ramkrishna (1994), for turbulent stirred tanks, as well as those of Davis et al (1989),.

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