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Studies, nevertheless, have been carried out to develop suitable catalysts and find effective reaction conditions Among all catalysts studied, Ru, Rh, and Ni supported on metal oxides exhibit the highest activity, and Ru has been reported to be the most selective 59- 61 The supports exert a marked influence on both the adsorption and specific activity of the metals In most cases, Ti0 2 is the best support material to achieve good catalyst performance,62,63 which is attributed to a strong electronic interaction between the metal and the support Carbon dioxide usually adsorbs dissociatively on noble metals, and hydrogen facilitates the adsorption 64 ,65 On supported Ru, Rh, and Pd catalysts, chemisorption of CO 2 in the presence of hydrogen leads to the formation of surface carbonyl hydride IR spectroscopic measurements revealed that carbonyl hydride and formate as well as surface carbon are present during the catalytic reaction.

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When a photograph is framed, the framer often mounts the image on a matte, which provides a different, contrasting background to make the photograph stand out. Fireworks uses the matte idea to allow the Web designer to export images with varying canvas colors without changing the canvas. One of the biggest problems with GIF transparency is the unwanted halos that result from creating a drop shadow or other gradation against a different background. The traditional method of handling this problem is to change your canvas color in the graphics program to match the background color on the Web page. This solution works well for graphics you re only going to use once, but many Web designers find that they need to use the same graphic in many different situations, against many different backgrounds. The Matte feature enables you to keep one master graphic and export as many specific instances against as many different mattes or canvases as necessary, as shown in Figure 15-11.

6o,62,66,67 On Ru on Ti0 2, CO and formate intermediates were identified 66 Dissociation of CO 2 promoted by hydrogen, the dissociation of surface carbonyl hydride into reactive surface carbon, and the hydrogenation of the latter are proposed as important steps in the hydrogenation process Surface formate located on the support was shown to be inactive undergoing decomposition, whereas formate located at the interface is the precursor for CO, which eventually leads to methane 66 Dissociation of intermediate formaldehyde was shown to be the rate-determining step over Rh on Si026o A metal-support interaction between Ru and the support that modifies the electronic state of the metal was found to be important when Ru was supported on HZSM_5 68 Doping Rh on Ti0 2 with W 6+, again, modifies the electronic state of Ru via electronic interactions.

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The resulting changes in the adsorption strength and the surface concentration of hydrogen and various intermediates lead to an enhanced catalytic activity69 Ru on Ce02 is also highly active, and promotion of Ru on Si02 with Ce02 results in substantial increase in catalytic activity O On increasing reduction temperature progressive reduction of Ce02 takes place Activation of CO 2 occurs with its interaction with Ce3+ producing CO and surface carbonaceous species71 The role of support was shown in a study using Rh on Si02 with different metal 10adings72 Over the 1% Rh on Si02 sample CO formed as a result of dissociative adsorption reacted with surface hydroxyl groups of silica to form Rh carbonyl clusters Because of the considerably higher metal coverage, the concentration of hydroxyl groups on the 10% Rh on Si02 catalyst is much lower.

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