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complexes This results in a working catalyst that is vastly superior to a fresh catalyst Stable acetate groups, but not the surface-bound acetyl groups, are formed and detected by FTIR On the basis of results acquired by various experimental techniques different mechanisms for the formation of ethanol and acetaldehyde have been suggested 526 Temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and XPS showed that the structure of the active sites may be formulated as (RhoxRh\)-O-M n + (M = Mn or Zr) The tilt adsorbed CO species is the main precursor for CO dissociation, which is directly hydrogenated to CH 2-O species followed by CH 2 insertion and hydrogenation to ethanol Acetaldehyde, in turn, is formed through insertion into surface CHrRh species and subsequent hydrogenation The role of the promoters is to stabilize the intermediate surface acetyl species.



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The 10Base or 100Base part of this code indicates that the cable is capable of supporting 10 Mbps or 100 Mbps bandwidth on a baseband (digital) signal. On the coax cable, the 5 and 2 indicate the maximum segment length of 500 meters and 200 meters of the two cable types, respectively. The number 200 is used for 10Base2 because it s easier to remember than 185, which is its actual maximum segment length. The T in 10BaseT refers to twisted pair cable, and fiber optic cable is designated with an F. The common designations for Ethernet cable are the following:

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Studies have been devoted to further elucidate the effects of structural changes of zirconia on activity and selectivity in isosynthesis and to acquire information on the mechanism of the formation of isomeric hydrocarbons Zirconia catalysts prepared by precipitation exhibit higher activity, while those prepared by a hydrothermal process show higher selectivity toward iso-C 4 products 527 Zr02 with 7% Ce02 is the most promising catalyst to afford fairly high conversion (25-40%) and reasonable selectivities (around 20%) Higher selectivity, again, is the main characteristic of catalysts made by the sol-gel method, which is due to increased basicity528 Basic sites were also found to affect the selectivity of the formation of isobutylene, whereas acidic sites increased the conversion of CO 529 Large differences in selectivities were observed over catalysts prepared by precipitation from various zirconium salts attributed to the presence of precursor anions in the hydroxide gel.

With the matrices {p(z), ( Z ) }so defined, we embed p(z) into a 2B x 2B circulant Q matrix C ( z ) , say, for B = 3,

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530 The product distribution of isosynthesis changed with increasing calcination temperature The highest selectivity to isobutane and isobutylene was observed on catalysts calcined at 500-700 C Tracer studies with BC showed that the carbon of methoxy species formed in CO hydrogenation appeared as the central C atom of isobutylene 531 Methoxy was shown to be reduced to surface methyl species that was transformed to surface acetyl group via insertion of CO into the methyl-metal bond Aldol condensation of C2 oxygenates with formaldehyde affords iso-C4 products 532 Earlier results of a different approach for isosynthesis using metal-zeolite catalyst systems are summarized in a 1998 review 533 Methanation, that is, the hydrogenation of carbon oxides, is a potentially important transformation Hydrogenation of CO 2 to methane, which has attracted great interest, is treated in Section 321.

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