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Our measurements show that the fraction of azobenzene side group that are bound into micelles is most typically signi cantly smaller than 100% Fig 76a gives representative UV-visible spectra of azo-modi ed polymers in water, as a function of the concentration of surfactant The absorbance obviously increases and the main peak is red-shifted with increasing the surfactant concentration, two features that re ect the transfer of azobenzene from water into a less polar environment The presence of isobestic points betrays that the azo groups are either in contact with water or tightly bound to the surfactant and no intermediate solvatation state is detected (not shown) The absorbance at a xed wavelength indicates accordingly the degree of binding of the azobenzene groups In Fig 76b, the absorbance abruptly increases above the critical micelle concentration (Khoukh et al, 2007).



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Table A-7: Values for NCurses colors COLOR 0 1 2 3 4 5 6 7 INIT_COLOR() FUNCTION init_color(0,0,0,0); init_color(0,1000,0,0); init_color(0,0,1000,0); init_color(0,1000,1000,0); init_color(0,0,0,1000); init_color(0,1000,0,1000); init_color(0,0,1000,1000); init_color(0,1000,1000,1000); CONSTANT NAME COLOR_BLACK COLOR_RED COLOR_GREEN COLOR_YELLOW COLOR_BLUE COLOR_MAGENTA COLOR_CYAN COLOR_WHITE

Sample output:





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In the case of other nanoparticles, such as proteins or polymers of CDs, the absorbance increases immediately upon addition of the particles (Pouliquen et al, 2007; Pouliquen and Tribet, 2006) At incipient binding, the association was considered very tight and quantitative, and it has not been possible to estimate a binding constant (not shown) The association was presumably strengthened because of multipoint attachments (see later) A saturation plateau can be reached at high concentrations of the nanoparticles Once normalized by the concentration of azobenzene and a reference shift of extinction coef cient (eg, as measured with azobenzene in water and dodecane), the plateau value should indicate the fraction of bound chromophore In practice, the normalized plateau value depends on the integration level of the azobenzene and intrachain repulsion (as modulated by ionic strength in the case of our azo-modi ed polyelectrolyte).

3, can_change_color(), COLORS, color_content()

24.09.2004 20:59

init_pair()

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In other words, variability of the molar absorption in the saturated state clearly indicates that a variable fraction of the chromophore remains unbound, even in presence of large excess of surfactant With neutral micelles of Triton X-100 and C12E4, the saturation could correspond to less than 50 mol% association (Fig 76b, right axis), which means formation of long polymer loops rather than short ones upon binding Incomplete association of the chromophores is presumably because of.

The init_pair() function assigns a foreground and background text color to a color pair value. The color pair value is then used with the COLOR_PAIR(n) attribute to apply those foreground and background colors to text or a window as a whole.

2) register Remote Object "A"

int init_pair(short pair, short f, short b);

3451 Photoinduced Contraction and Expansion of LCEs Light as a stimulus enables noncontact activation at ambient temperature In this way, external heating, which is unfavorable for certain applications and is used to stimulate conventional deformable polymers, can be avoided; thus, decades of intensive studies as aforementioned have focused on the discovery of photoresponsive polymer systems that exhibit fast and large macroscopic shape changes As described in Section 343, LCEs show thermoelastic properties: upon transition from the nematic to the isotropic phase, they contract along the alignment direction of mesogens, and upon cooling below the phase transition temperature, they expand If this property of LCEs is combined with photochemical phase transition (or photochemically induced decrease of nematic order), it is expected that deformation of LCEs can be induced by light (Cviklinski et al, 2002; Hogan et al, 2002; Finkelmann and Nishikawa, 2001).

pair is a short int value representing a color pair number. Values range from 0 through the value of the COLOR_PAIR constant, minus 1. The color pair number is used to reference the foreground/background text color combination, specifically with the COLOR_PAIR(n) attribute. The n in COLOR_PAIR(n) is the same as pair, representing the color pair created.

In fact, Finkelmann and coworkers succeeded in inducing a contraction by 20% in an azobenzenecontaining LCE (Components 17a f) upon exposure to UV light to cause the trans cis isomerization of the azobenzene moiety (Fig 321) (Finkelmann and Nishikawa, 2001) They synthesized monodomain nematic LCEs with polysiloxane main chains and azobenzene chromophores at the cross-links From the viewpoint of photomechanical effects, the subtle variation in nematic order upon trans cis isomerization causes a signi cant uniaxial deformation of the LCs along the director axis when the LC molecules are strongly associated by covalent crosslinking to form a three-dimensional polymer network Terentjev and coworkers incorporated a wide range of azobenzene derivatives into LCEs as photoresponsive moieties and examined their deformation behavior upon exposure to UV light ( Cviklinski et al, 2002; Hogan et al, 2002).

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