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3.4.4.3. Photochemical Phase Transition of Azobenzene LC Polymers. LC polymers possess properties of both polymers and LCs and currently are regarded as promising photonic materials because of their advantageous properties mentioned earlier. Wendorff and coworkers reported the rst example of a photon-mode photoresponse in LC polymers, namely, holographic recording in LC polymer lms containing azobenzene moieties and mesogenic groups (Eich et al., 1987; Eich and Wendorff, 1987). Ikeda et al. (1990a,b, 1988) reported the rst example of the photochemical phase transition in LC polymers; they demonstrated that by irradiation of LC polymers doped with LMW azobenzene derivatives with UV light to cause trans cis isomerization led to a nematic isotropic phase transition; upon cis trans back-isomerization, the LC polymers reverted to the initial nematic phase. Although doping the chromophores in a matrix is most convenient, the resultant LC polymer systems often exhibit instabilities, such as phase separation and microcrystallization. This occurs because of the mobility of the azobenzene chromophores in the matrix and the propensity of the dipolar azobenzene units to form aggregates. Higher quality LC polymer systems are obtained when the azobenzene moiety is covalently bound to the host polymer matrix, and this approach is now preferable for most applications. These materials combine the stability and processability of LC polymers, with the unusual photoresponsive behavior of the azobenzene groups. A variety of



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E E E The most obvious difference between CLIENT-DEPENDENT INSTANCES and using STATIC INSTANCES and PER-REQUEST INSTANCES is that an additional component is introduced, the factory. This is necessary to allow clients to request a CLIENT-DEPENDENT INSTANCE that is specific to the client. In the case of a STATIC INSTANCE or a PERREQUEST INSTANCE, creation and activation of the remote object is handled by the SERVER APPLICATION and/or the distributed object middleware. The factory itself is typically a STATIC INSTANCE. When invoked by a client, it creates the requested CLIENT-DEPENDENT INSTANCE and returns the ABSOLUTE OBJECT REFERENCE of the newly-created instance to the client. As explained above, CLIENT-DEPENDENT INSTANCES typically are considered to be accessed by a single client only. As a consequence, no concurrency issues need be taken care of in the servant, with regard to client requests and its own state. If CLIENT-DEPENDENT INSTANCES can be accessed concurrently (for example, because a client can open multiple browser windows that are not coordinated), some kind of synchronization has to be implemented on the server side.

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LC copolymers were prepared, and their photochemical phase transition behavior was examined (Tsutsumi et al, 1998a; Sasaki et al, 1992; Ikeda et al, 1990b,c) One of the important factors of the photoresponsive LCs is their responses to optical stimuli In this respect, the response time of the photochemical phase transition has been explored by time-resolved measurements (Sasaki et al, 1992; Ikeda et al, 1991; Kurihara et al, 1990) Photochromic reactions are in general very fast, occurring on a timescale of picoseconds If an ultrafast laser with a pulse width on the picosecond scale is used as an excitation light source to induce phase transitions of LC systems containing photochromic molecules, photochemical reactions of the photochromic molecules can be completed in picoseconds, and the Tc of the system can be decreased below the irradiation temperature on this timescale.

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Lifecycle Management Patterns In addition, access to global shared resources from within CLIENTDEPENDENT INSTANCES still needs to be serialized. To ensure that only one client accesses a CLIENT-DEPENDENT INSTANCE, the factory will only provide operations to create new instances. It is not possible to ask the factory to return some previously-created instance. The client therefore has to store the reference to the instance, and it is the client s own responsibility whether to pass the reference to other clients. Lifecycle management of CLIENT-DEPENDENT INSTANCES is easy if clients behave well. The clients are required to signal when to destroy the remote object, permitting the server application to remove the servant from memory. However, if a client forgets to invoke destroy, or if a client crashes, the server application may end up with orphan CLIENT-DEPENDENT INSTANCES. To avoid this, LEASING [KJ04] is used. This allows the removal of orphan CLIENT-DEPENDENT INSTANCES when the lease period expires. There are potential problems with the lifecycle model of CLIENT-DEPENDENT INSTANCES, though. The more clients a server application has, the more CLIENT-DEPENDENT INSTANCES might be created. Thus the server

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