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Ideally, one polymer segment with low chromophore density could bind onto the particle and form cross-links that contain just a few azobenzene groups (Fig 78a) instead of several tens in a micelle of azo-surfactant Extremely low concentrations of cross-links (submillimolar, or even micromol, concentrations in common soft gels) match well the requirement for low concentration of hydrophobic photochromes Other advantages expected from this approach include (i) the versatility of tuning the viscosity/elasticity by adjusting the concentrations of nanoparticles and azopolymers, with no chemical modi cation and limited variation of absorbance, (ii) ampli cation of the response at both the stage of particle binding (see previous paragraph) and by the sol gel transition The nanoparticles tested to date include micelle of conventional surfactants (Pouliquen et al, 2002), proteins (Pouliquen and Tribet, 2006), and oligomers of CDs (Pouliquen et al, 2007) In Fig 7.



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8b, the elastic and loss moduli of samples containing the same polymer concentration and increasing protein concentration show the change from sol- to gel-like properties: at the critical protein concentration, both moduli display the same dependence on frequency (GBon) that betrays the presence of polydisperse clusters of chains At higher protein concentrations, the gel-like nature of samples is characterized by a large frequency window showing a plateau of Gu (naturally for frequency much higher than the reciprocal lifetime of associations) This pseudorubbery plateau is essentially proportional to the density of cross-links Experimentally, both elastic and loss moduli vary abruptly while crossing the critical gel point composition (Fig 78b) In turn, a photovariation of the fraction of bound nanoparticle would switch the systems between a sol- and gel-like behavior.

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The properties of semidilute mixtures of the protein bovine serum albumin and azopolymers match well with the simple idea of a photodestruction of the cross-links As shown by stress relaxation experiments, the shear modulus (at time zero in Fig 79a) is markedly diminished by exposure to UV, whereas the chain dynamics and relaxation time(s) appear not signi cantly affected A decrease by more than a factor of 10 of the modulus indicates clearly the dissociation of most interchain associates (Fig 79b) Nevertheless, the dissociation of the protein polymer complexes may not occur when the cross-links disappear As pointed by Leibler and colleagues in the case of interpolymer complexes (Pezron et al, 1988), and by Borrega in the case of protein polymer physical gels (Borrega et al, 1999),.

int scr_set(const char *filename);

The scr_set() function is equivalent to a call to scr_init() followed by a call to scr_restore(). Refer to scr_init() or scr_restore() for more information.

that under proper conditions, uniform colloidal spheres can be obtained from the polydispersed amphiphilic azo polymers. The colloid formation, preparation conditions, and possible mechanism will be discussed in the following sections.

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The scr_set() function loads window data from a file referenced by the fname (string) variable. Both the window s settings and visual data are

The polydispersed amphiphilic azo homopolymers and random copolymers, such as those given in Figs. 5.1 and 5.2, can form uniform colloidal spheres through gradual hydrophobic aggregation process (Li et al., 2006a, 2005a). In a typical process, the colloids are formed by slowly dropping deionized water into diluted solutions of the polymers in a proper solvent such as THF. The method is similar to those developed by Eisenberg and coworkers. to prepare micellelike aggregates from solutions as mentioned earlier. It can be observed that when the water content reaches a critical content, the light-scattering intensity abruptly increases, which indicates that the polymeric chains in the solutions start to aggregate. This water content is also named as the CWC. The aggregation can be completed by gradually increasing the water content in the system. After this, the structure formed in the suspensions can be frozen by adding excess water into the suspensions. Stable water suspensions of the colloidal spheres can be obtained by removing THF from the systems through dialysis. Figure 5.3 shows some typical scanning electron microscopy (SEM) images of the colloidal spheres of PEAPE separated from the suspension. The chemical structure of the polymer can be seen in Fig. 5.2, and the DF of the polymer is 49.9%, de ned as the percentage

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