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Figure 2.9. Optical anisotropy induced by the light in a lm of the compound Alizarin Yellow GG-PEI: kinetics of the parallel (dashed black line) and orthogonal (solid gray line) polarization components of the transmitted probe beam. (a) Induction and relaxation, solid black line presents two-exponential decay t to the data, and (b) switching by alternation of polarization of the irradiating beam. Source: Kulikovska et al., 2007. Reproduced with permission from American Chemical Society.

char text[] = Hello there, handsome! ; char *t; t = text; initscr(); while(*t) echochar(*t++); getch(); endwin(); return 0; }

Sample output:



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Figure 2.10. Chemical structure of complexes of poly(vinyl-N-alkylpyridinium) with Methyl Orange and the Ethyl Orange (EO) with C12D and C16D surfactants.

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Hello there, handsome!

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The maximum value of photoinduced birefringence achieved were 0067 and 031 for ethyl- and methyl-quaternized polyvinylpyridine (see Fig 210a), respectively (Zhang et al, 2008; Xiao et al, 2007) The authors believe that such a great difference in photoorientation properties is hardly attributed to structural difference consisting of one methylene group, but more probably to the difference in synthesis, puri cation, lm preparation, etc A rather simple approach for design of low-molecular-weight ionic supramolecular complexes has been recently proposed (Zakrevskyy et al, 2005, 2004; Guan et al, 2003) These new materials are formed by introduction of oppositely charged ions between different low molecular tectonic units and are called ISA complexes In contrast to the discussed LbL and polyelectrolyte-based ionic complexes, the polymer unit is usually replaced by low-molecular-weight surfactant.

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G. Kiczales, E. Hilsdale, J. Hugunin, M. Kersten, J. Palm, G. Griswold: Getting Started with AspectJ, Communications of the ACM, 44 (10): 59 65, October 2001 M. Kircher and P. Jain: Pattern-Oriented Software Architecture Patterns for Resource Management, John Wiley & Sons, 2004 G. Kiczales, J. Lamping, A. Mendhekar, C. Maeda, C. V. Lopes, J. M. Loingtier, J. Irwin: Aspect-Oriented Programming, Proceedings of the 11th European Conference on Object-Oriented Programming (ECOOP 97), Jyv skyl , Finland, LCNS 1241, Springer-Verlag, June 1997 H. Kopetz: Real-Time Systems Design Principles for Distributed Embedded Applications, Kluwer Academic Publishers, Boston, Dordrecht, London, 1997 J.-C. Laprie: Dependability: Basic Concepts and Terminology, Proceedings of the 15th International Symposium on Fault-Tolerant Computing (FTCS15), Michigan, USA, June 1985 D. Lea: Concurrent Programming in Java Design Principles and Patterns, Addison-Wesley, Second edition, 1999 D. B. Lange and M. Oshima: Programming and Deploying Java Mobile Agents with Aglets, Addison Wesley, 1998 J. Lowy: Decouple Components by Injecting Custom Services into Your Object s Interception Chain, MSDN Magazine, March 2003 http://msdn.microsoft.com/msdnmag/issues/03/03/ ContextsinNET/default.aspx

endwin()

Application of the ISA concept to produce photosensitive low-molecularweight materials with good lm-forming properties, which are capable of undergoing light-induced generation of optical anisotropy, has been proved to be very successful (Zakrevskyy et al, 2006a) The photosensitive ISA complexes consist of charged azobenzene-containing photosensitive units complexed with oppositely charged surfactants The chemical structure of the most detailed investigated complexes is shown in Fig 210b Other examples of the photosensitive complexes can be found in a study by Zakrevskyy et al (2006b) It should be noted that proper design of ISA complexes, based on functionalized tectonic units and surfactants, results in a new strategy for creation of functionalized liquid crystals This approach can lead to speci c optical functions of the material Induction of optical anisotropy in spin-coated lm of the ISA complexes under irradiation with polarized light of an Ar+ laser was very effective (Zakrevskyy et al.

int endwin(void);

endwin() is required at the end of a NCurses program to undo what was done by either initscr() or newterm(), and to restore terminal behavior.

[KJ04] [KLM+97]

, 2007) Dichroic ratios of 50 for the EO C12D complex and of 20 for the EO C16D complex have been obtained (Fig 212a and b) To the best of the authors knowledge, this is the highest value of photoinduced anisotropy It was shown that both complexes exist in highly ordered columnar LC phases at room temperature, and their photobehavior is strongly affected by their liquid crystallinity Spin-coated lms of the complexes are built from LC domains The photoalignment of the complexes depends strongly on the size of the domains In the case of small domains, the photoalignment is the most effective Photoreorientation in the complexes is not local like in azobenzene-containing polymers, but is a cooperative process and connected to mechanical rotation of domains..

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