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Natural diamond has been in use for grinding very hard non-ferrous materials, notably glass and ceramics, since about 1890 for saws and since about 1940 for cutting tools [31] Natural diamond develops slowly at temperatures from 900 to 1,300 C and pressures from 40 to 60 atm It is extracted from nodules of Kimberlite, which is a variety of mica, peridotite low in silica and high in magnesium, in which natural diamonds are formed and grown Natural diamonds come in various forms and colours: (a) Large single crystals monocrystalline (b) Carbonadoes or balas polycrystalline (c) Borate single crystal monocrystalline Large single crystals, because of their lustre, are used as gems and are extremely costly Borat, an inferior single-crystal diamond, is used for making cutting tools in ductile mode machining However, it suffers from cleavage problems It is easily cleaved on planes that are parallel with the octahedral faces because the density of inter-atomic bonding is the lowest on these faces [32] Thanks to advances in the machining of diamonds, it is possible to locate the strongest plane (ie, the {110} plane) in the main cutting force direction, thus avoiding cleavage and minimizing wear The demands posed by the cleavage problem of single-crystal diamonds have also been met by nature; balas and carbonados, which are natural polycrystalline masses of diamonds They consist of small grains of diamonds 10 100 in size bonded together The random orientation of their grains blocks tile propagation of any cleavage plane that may start in a highly stressed region However, the shortage of these natural polycrystalline diamonds has increased the demand for synthetic diamonds



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Fig. 12-3.

Synthetic diamonds were developed by GE in 1955 and also probably by the USSR round about the same time These are made by heating graphite to a high temperature of 3,000 K and at a high pressure of 125 kilobars with nickel being used as a catalyst (Figure 225) Here the hexagonal arrangement of atoms in amorphous carbon (graphite) is converted into a cubic arrangement of





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atoms in crystalline carbon (diamond) as shown in Figure 226 [33] Graphite first dissolves into the catalyst and is then converted into diamond at appropriate pressure and temperature conditions within the diamond stable region Since the size of a diamond increases with time, the reaction conditions are normally maintained for several minutes when larger grits are desired Nickel has the advantage that graphite dissolves in it, but when converted to diamond, it is insoluble Other than nickel, chromium, manganese, tantalum and all elements of Group VIII of the periodic table are effective as catalysts It is difficult to make large single-crystal diamonds synthetically Synthetic diamond powder that is sintered rapidly at high pressures and high temperatures into moulded shapes It is manufactured by Mega diamond industries in the US

Fig. 12-4.

Fig 226: Transformation of the hexagonal arrangement of atoms in graphite to a cubic arrangement in diamond [33]

N-type semiconductor (silicon and phosphorus).

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Since sintered diamonds, like other sintered products, can be shaped, applications such as wire drawing dies, grinding wheel dresses, small grinding wheels, small styli, wedges, and points are possible GE, on the other hand, has developed diamond compacts, which have a layer of polycrystalline aggregates of a thickness of at least 05 mm on a tungsten carbide substrate By placing small-grainsized diamonds on the carbide surface and subjecting them to a high temperature and a high pressure, good bonding takes place by cobalt diffusion Diamond compacts are excellent for machining nonferrous alloys, fibreglass bodies, graphite and other highly abrasive materials They however perform poorly on steel, titanium alloys and stainless steel largely because of carbon diffusion into iron [34] The synthetic single crystal diamond is widely commercialized for making single point single crystal diamond tools for ultra-precision cutting processes (see Figure 230) such as for machining moulds, laser mirrors, magneto-optical discs, optical lenses and has important applications in industrial fields such as the electronic industry and in optical technology

244 Polycrystalline Diamond (PCD)

Fig. 12-5. P-type semiconductor (silicon and boron).

Polycrystalline diamonds consist of very small synthetic crystals They are synthesized from graphite at a high temperature (3,000 K) and a high pressure (125 kbars) in the presence of a molten solvent (Ni) to a thickness of about 05 to 1 mm Diamond is sintered onto a carbide substrate with cobalt as a binder Figure 227 illustrates the synthesis of polycrystalline diamond PCD can be considered to

Fig 227: Synthesis of a polycrystalline diamond [22, 35]

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