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Absorption, 211 Acetaldehyde in aldol reaction, 100 BF3 a nity, 123 IP, 123 PA, 123 pKb , 123 pyruvate decarboxylase, 302 by Wacker process, 293 Acetic anhydride, 281 Acetoacetone asymmetric reduction of, 12 pKa , 142 Acetone, 278 BF3 a nity, 123 IP, 123 PA, 123 pKa , 142 pKb , 123 Acetonitrile pKa , 142 Acetylene complex with ozone, 304 pKa , 142 point group of, 5 Acetylenes cyclic di-, IP, 305 Acetylacetonate (acac) as chelating ligand, 186



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cleavage of the C X bond and may have substantial carbocationic character. Factors which favor carbocation formation will also lower the energy of the transition state. Thus, X: or ``C'' substituents will accelerate the rate of the rst step. The reaction is reversible. The reverse reaction provides the mechanism for the conversion of alcohols to alkyl halides. Polar solvents are necessary in order to stabilize the resulting ions. However, the direct nucleophilic involvement of solvent in the solvolysis of derivatives of tertiary C is a matter of debate [209]. We noted earlier that heterolytic rupture is easiest for the C X bond and most di cult for C C in the series C C, C N, C O, and C F:

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H o w organisations manage knowledge using the Internet, leveraging both tacit and explicit knowledge to create a superior organisation succeeding in all its activities, is a key driver of growth and profitability and an issue that is explored in this chapter. O n e of the greatest advantages of e-business is the explosion in knowledge across a broad range of areas including customers, markets and internal organisational developments. Managing this broad scope of expertise and knowledge can be accomplished in a way that brings competitive advantage, but it requires specific skills and techniques. Knowledge and human capital are old concepts; what is new is the understanding that information and knowledge have t o be defined, nurtured, developed, managed and used just like any other strategic resource o r asset. Achieving this can provide cascading benefits throughout the organisation, delivering profitability at

The single most important design issue facing the data warehouse developer is determining the proper level of granularity of the data that will reside in the data warehouse. When the level of granularity is properly set, the remaining aspects of design and implementation flow smoothly; when it is not properly set, every other aspect is awkward. Granularity is also important to the warehouse architect because it affects all the environments that depend on the warehouse for data. Granularity affects how efficiently data can be shipped to the different environments and determines the types of analysis that can be done. The primary issue of granularity is that of getting it at the right level. The level of granularity needs to be neither too high nor too low. The trade-off in choosing the right levels of granularity (as discussed in 2) centers around managing the volume of data and storing data at too high a level of granularity, to the point that detailed data is so voluminous that it is unusable. In addition, if there is to be a truly large amount of data, consideration must be given to putting the inactive portion of the data into overflow storage.

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