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In fact, these relations only determine the ratio between currents and voltages at input and output ports of the active device; their absolute value, or rather the operating power, is xed by other considerations, as for example gain saturation of the active device. A typical transistor has a gain saturation characteristic as in Figure 5.22. The input operating power Pin,0 at which the admittance parameters are evaluated can be chosen as that maximising the added power Pout Pin [7, 10, 11]; this choice sets the absolute value of the voltages and currents at the input and output ports of the transistor at which the admittance parameters are measured and at which the design is performed.

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Compounds with a low HOMO and LUMO (Figure 55b) tend to be stable to selfreaction but are chemically reactive as Lewis acids and electrophiles The lower the LUMO, the more reactive Carbocations, with LUMO near , are the most powerful acids and electrophiles, followed by boranes and some metal cations Where the LUMO is the s of an H X bond, the compound will be a Lowry Bronsted acid (proton donor) A Lowry Bronsted acid is a special case of a Lewis acid Where the LUMO is the s of a C X bond, the compound will tend to be subject to nucleophilic substitution Alkyl halides and other carbon compounds with ``good leaving groups'' are examples of this group Where the LUMO is the p of a C X bond, the compound will tend to be subject to nucleophilic addition Carbonyls, imines, and nitriles exemplify this group.

(4.46)

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Compounds with a high HOMO and LUMO (Figure 55c) tend to be stable to selfreaction but are chemically reactive as Lewis bases and nucleophiles The higher the HOMO, the more reactive Carbanions, with HOMO near , are the most powerful bases and nucleophiles, followed by amides and alkoxides The neutral nitrogen (amines, heteroaromatics) and oxygen bases (water, alcohols, ethers, and carbonyls) will only react with relatively strong Lewis acids Extensive tabulations of gas-phase basicities or proton a nities (ie, hG of protonation) exist [109, 110] These will be discussed in subsequent chapters Compounds with a narrow HOMO LUMO gap (Figure 55d ) are kinetically reactive and subject to dimerization (eg, cyclopentadiene) or reaction with Lewis acids or bases Polyenes are the dominant organic examples of this group.

AN UNRELATED MOMENT OF PAUSE BARBECUE CHICKEN NACHOS (continued)

The di culty in isolation of cyclobutadiene lies not with any intrinsic instability of the molecule but with the self-reactivity which arises from an extremely narrow HOMO LUMO gap A second class of compounds also falls in this category, coordinatively unsaturated transition metal complexes In transition metals, the atomic n d orbital set may be partially occupied and/or nearly degenerate with the partially occupied n 1 sp n set Such a con guration permits exceptional reactivity, even toward C H and C C bonds These systems are treated separately in 13..

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End-of-life vehicles: recycling collection, 581 583 recycling process, 727 728 Energy crisis: coatings, 212 environment, 11 16 Energy recovery, recycling technology, 565, 615 617 Energy requirements, 123 135 contributions to, 124 conversion processes, 132 133 feedstock, 125 gross and net calori c values, 127 128 gross energies, typical, 128 132 historical perspective, 123 124 packaging, 166 177 recycling, 133 135 representations, 126 127 transportation, 125 126 Engine throttle body, automotive polymers, 742 Environment, 3 75 automobile applications, 730 731 business enterprises, 18 25 energy crisis, 11 16 global warming, 62 68 marine environment, 385 389. See also Marine environment materials crisis, 17 18 overview, 3 11 ozone depletion, 69 75 packaging, 166 177 perspectives on, xiii xv polyethylene manufacture, 92 93 polymer industry, 32 50. See also Polymer industry polyvinyl chloride, 98 101 proactive treatment, 56 57 stewardship responsibility, 27 32, 56 consumers, 30 31 government, 31 32 industry, 27 29 valuation methods, 25 27 Environmental weathering tests: described, 339 342 laboratory-accelerated weathering tests compared, 351 352 Epibionts, marine environment, 386 388 Epoxy binders, 216

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