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The most striking observation about these results is that it takes a pressure change of more than 40 bar to have an effect on the excess Gibbs energy equivalent to that of a temperature change of 1 K (1 C) Similar calculations based on Eqs (1193) and (1194) produce similar results This is the reason that for liquids at low pressures the effect of pressure on the excess Gibbs energy and on the activity coefficients is usually neglected Just as the fundamental property relation of Eq (1150) provides complete property information from a canonical equation of state expressing G I R T as a function of T, P , and composition, so the fundamental residual-property relation, Eq (1151) or (1 152), provides complete residual-property information from a P V T equation of state, from P V T data, or from generalized P VT correlations However, for complete property information, one needs in addition to P V T data the ideal-gas-state heat capacities of the species that comprise the system In complete analogy, the fundamental excess-property relation, Eq (1186) or (1 189), provides complete excess-property information, given an equation for GE/RT as a function of its canonical variables, T, P, and composition, However, this formulation represents lesscomplete property information than does the residual-property formulation, because it tells us nothing about the properties of the pure constituent chemical species

Part I:

referred to directly, as if they were part of B Even though A is a superclass for B, it is also a completely independent, stand-alone class Being a superclass for a subclass does not mean that the superclass cannot be used by itself Further, a subclass can be a superclass for another subclass The general form of a class declaration that inherits a superclass is shown here: class subclass-name extends superclass-name { // body of class } You can only specify one superclass for any subclass that you create Java does not support the inheritance of multiple superclasses into a single subclass (This differs from C++, in which you can inherit multiple base classes) You can, as stated, create a hierarchy of inheritance in which a subclass becomes a superclass of another subclass However, no class can be a superclass of itself

Name fillText(text, x, y [, maxWidth])

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Peculiarities of liquid-mixture behavior are dramatically revealed in the excess properties Those of primary interest are GE, H E , and sE The excess Gibbs energy comes from experiment through reduction of vaportliquid equilibrium data, and H E is determined by mixing experiments (Chap 12) The excess entropy is not measured directly, but is found from

Description Writes text at location (x,y) and fills it according to the fillStyle The text is written according to the values set for font, textAlign, and textBaseline Sets the font for a text string Must be in the same format as CSS fonts The default is 10px sansserif Returns a TextMetrics object for the given text Currently, the only property for that object is width Writes text at location (x,y) according to the strokeStyle The text is written according to the values set for font, textAlign, and textBaseline Sets the alignment of a text string The x, y points specified will line up according to the option chosen The options are start, end, left, right, and center The default value is start Sets the text baseline for a text string The options are top, hanging, middle, alphabetic, ideographic, and bottom The default value is alphabetic

Although a subclass includes all of the members of its superclass, it cannot access those members of the superclass that have been declared as private For example, consider the following simple class hierarchy: /* In a class hierarchy, private members remain private to their class This program contains an error and will not compile

Example contextfont = "30px sans-serif"; contextfillStyle = "rgba (0, 255, 0, 5)"; contextfillText("Canvas is great!", 10, 40); contextfont = "bold 20px Courier New";

Eq (1183), written:

// Create a superclass class A { int i; // public by default private int j; // private to A void setij(int x, int y) { i = x; j = y; }

measureText(text)

Excess properties are often strong functions of temperature, but at normal temperatures are not strongly influenced by pressure Their composition dependence is illustrated in Fig 114 for six binary liquid mixtures at 32315 K (50 C) and approximately atmospheric pressure For consistency with Eq (1183), the product T S E is shown rather than S E itself Although the systems exhibit a diversity of behavior, they have common features: 1 All excess properties become zero as either species approaches purity 2 Although G E VS X I is approximately parabolic in shape, both H~ and T S exhibit indi~ vidualistic composition dependencies 3 When an excess property M E has a single sign (as does G E in all six cases), the extreme value of M E (maximum or minimum) often occurs near the equimolar composition

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