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// A's j is not accessible here class B extends A { int total; void sum() { total = i + j; // ERROR, j is not accessible here }

contextfont = "bold 20px Verdana"; tm = contextmeasureText ("I love Canvas"); var width = tmwidth; contextfont = '30px sans-serif'; contextstrokeStyle = "orange"; contextstrokeText('Canvas is great!', 10, 40);

strokeText(text, x, y [, maxWidth])

class Access { public static void main(String args[]) { B subOb = new B(); subObsetij(10, 12); subObsum(); Systemoutprintln("Total is " + subObtotal);

Feature 1 is a consequence of the definition of an excess property, Eq (1182); as any xi approaches unity, both M and M" approach M i , the corresponding property of pure species i Features 2 and 3 are generalizations based on observation, and admit exceptions (note, eg, the behavior of H~ for the ethanollwater system) A detailed discussion of excess-property behavior is given in Sec 166

contexttextAlign = "end";

- 136 -

contexttextBaseline = "ideographic";

.

TABLE 3-20

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This program will not compile because the reference to j inside the sum( ) method of B causes an access violation Since j is declared as private, it is only accessible by other members of its own class Subclasses have no access to it Note A class member that has been declared as private will remain private to its class It is not accessible by any code outside its class, including subclasses

111 What is the change in entropy when 07 m3 of C02 and 03 m3 of N 2 , each at 1 bar and 29815 K (25 C) blend to form a gas mixture at the same conditions Assume ideal gases 112 A vessel, divided into two parts by a partition, contains 4 mol of nitrogen gas at 34815 K (75 C) and 30 bar on one side and 25 mol of argon gas at 40315 K (130 C) and 20 bar on the other If the partition is removed and the gases mix adiabatically and completely, what is the change in entropy Assume nitrogen to be an ideal gas with Cv = (5/2)R and argon to be an ideal gas with Cv = (3/2)R 113 A stream of nitrogen flowing at the rate of 2 kg s-' and a stream of hydrogen flowing at the rate of 05 kg s-I mix adiabatically in a steady-flow process If the gases are assumed ideal, what is the rate of entropy increase as a result of the process 114 What is the ideal work for the separation of an equimolar mixture of methane and ethane at 44815 K (175 C) and 3 bar in a steady-flow process into product streams of the pure gases at 30815 K (35 C) and 1 bar if T, = 300 K 115 What is the work required for the separation of air (21-mol-% oxygen and 79-mol-% nitrogen) at 29815 K (25 C) and 1 bar in a steady-flow process into product streams of pure oxygen and nitrogen, also at 29815 K (25 C) and 1 bar, if the thermodynamic efficiency of the process is 5% and if T, = 300 K 116 What is the partial molar temperature What is the partial molar pressure Express results in relation to the T and P of the mixture 117 Show that: (a) The "partial molar mass" of a species in solution is equal to its molar mass (b) A partial speciJic property of a species in solution is obtained by division of the partial molar property by the molar mass of the species 118 If the molar density of a binary mixture is given by the empirical expression:.

3:

Let's look at a more practical example that will help illustrate the power of inheritance Here, the final version of the Box class developed in the preceding chapter will be extended to include a fourth component called weight Thus, the new class will contain a box's width, height, depth, and weight // This program uses inheritance to extend Box class Box { double width; double height; double depth; // construct clone of an object Box(Box ob) { // pass object to constructor width = obwidth; height = obheight; depth = obdepth;

Name createImageData(w, h) createImageData (imagedata)

119 For a ternary solution at constant T and P, the composition dependence of molar property M is given by:

// constructor used when all dimensions specified Box(double w, double h, double d) { width = w; height = h; depth = d; } // constructor Box() { width = -1; height = -1; depth = -1; } used when no dimensions specified // use -1 to indicate // an uninitialized // box

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