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In the case of electrically switchable gratings, LCs remain the material of choice because of the ease of molecular reorientation under the effect of a voltage The photoisomerization of azobenzene should play the role of trigger for the grating formation Self-assembled LC gels combine the property of electric eld orientation of LCs and the possibility of a structural rearrangement induced by the photoisomerization of the azobenzene gelator Even though the grating obtained from the cholesteric LC gel as described in Section 114 falls short for practical applications, the interest of exploiting self-assembled LC gels is clear, since this approach may be generalized for many systems made from designed gelators and various types of LCs The key to the grating formation process in self-assembled LC gels is the dissolution of the physical network in the LC host in irradiated areas.

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This may be enhanced by using azobenzene gelators whose cis form has a signi cantly higher polarity than the trans form, which increases the surface tension of the brous aggregates It also helps if the gelator could form very thin nano brous aggregates giving rise to a large speci c surface and thus a signi cant number of gelator molecules on the surface undergoing the trans cis photoisomerization Finally, further research effort is worth being made on materials for recording optically switchable diffraction gratings Optical control of optical properties, such as the diffraction, is not only academic curiosity but required for the.

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It then proceeds with its work The Web Service receives this invocation, sending a reply message back after processing the message The client also acts as a messaging server able to receive replies In JMS a JMSListener within the client waits for messages When a message arrives, the JMSListener uses the correlation identifier sent back with the reply message to look up the associated callback operation, and invokes it Even though this scheme follows the RESULT CALLBACK pattern, problems might occur Messaging protocols deal with a lot of additional aspects to support the QoS property reliability of message transfer In cases in which reliable message transport is not required, a messaging protocol is an overhead Also, if HTTP is used, the messaging protocol might be problematic In such cases we can implement the asynchrony patterns on top of synchronous invocations: this is explained in the next section.

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development of advanced photonic devices. The dynamic control (switching) of local optical properties by light instead of an electric eld offers the advantage of having no need for patterning transparent electrodes, which can be useful for certain applications. The discussed switching mechanism based on the photochemical phase transition (Section 11.5) induced by azobenzene s photoisomerization is particularly appealing. However, a common problem with both PSLCs (Tong et al., 2005a,b; Urbas et al., 2004a) and PDLCs (Urbas et al., 2004b) is that a thorough segregation of azobenzene molecules from the polymer areas is dif cult to achieve, so that the photoisomerization not only affects the LC host as desired but also affects the polymer. This may limit the index modulation depth and thus the switching performance. For future studies, the grating fabrication method should not be limited to the photopolymerization-induced phase separation (holographically or not). For instance, if a method allows for ef cient alternative deposition of two SLCPs with controlled layer thickness in the order of 200 nm, an effective re ection grating (Bragg re ector) can be designed to have one SCLCP having a low Tg (below or close to room temperature) and bearing azobenzene mesogens, whereas the other SCLCP can be chosen to have a high Tg and contain nonazobenzene mesogens. In this case, after aligning both polymers (e.g., by rubbed surfaces at temperatures above both Tgs), upon UV light irradiation at room temperature, the photochemical LC-to-isotropic phase transition can occur only in layers of the azobenzene SCLCP, which should have no effect on the other SCLCP remaining aligned. This would resolve the phase separation problem as mentioned earlier.

Building asynchrony patterns on top of Axis In this section we explain how to implement the client-side asynchrony patterns on top of Axis in a generic and efficient way To achieve this we implement an asynchrony Layer on top of the synchronous invocation Layer provided by Axis Please note that there is a certain overhead associated with this implementation, so that native support of a framework for asynchrony should generally be preferred..

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