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This program inches through a string of text using a pointer t. The pointer allows each character in the string to be displayed one at a time via the addch() function. The napms() function pauses output one-tenth of a second between each character displayed, which helps to drive home the nature of addch(). I ll cover napms() in more detail in the next section.



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molecules can affect the formation of molecular aggregates (Stumpe et al, 1996; Shimomura, 1993), induce phase transitions in the material (Hasegawa et al, 1999), or change the enzyme activity (Willner et al, 1991) Recently, the photoinduced change of the geometric shape of macroscopic objects has been demonstrated (Ikeda et al, 2007; Bublitz et al, 2000; Seki et al, 1996) If the irradiating light activates both E Z and back Z E transitions, the steady state of photoreaction is established, whereas the molecules undergo repeated isomerization cycles In many cases, it is not an equilibrium concentration of both isomeric forms that is important, it is the light-induced dynamics, that is, the continuing movement of the chromophore.

screen until you refresh!

[BMR+96]

In addition to all the fun screen (and soon-to-come keyboard) frivolity, NCurses also features a variable pausing function, napms(). Such a cute name!





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In other words, the isomerizing azobenzene molecule works as a light-driven molecular motor, whose power and force direction may be controlled by the parameters of the irradiating light, such as wavelength, polarization, or intensity distribution This statement is kept in mind when discussing the photoinduced processes in this chapter The irradiation with polarized light results in the preferential orientation of azobenzene molecules perpendicularly to the light electric eld vector orientational order is induced, the system becomes anisotropic The photoinduction of molecular order causes plenty of macroscopic effects, including optical anisotropy, which is one of the subjects in this chapter After the actinic light is switched off, the photoproduct reacts back to the thermally stable E isomeric form and the initial state is restored at the molecular level It may be changed thermally or by irradiation with actinic light.

napms(ms)

[BN84] [Bor04]

The napms() function pauses program execution for ms milliseconds. So the statement:

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The uniformity of the photoreaction and rebuilding of the initial state at the molecular level guarantee the complete reversibility of the processes Note that an important advantage of azobenzenes is that both photoisomerization processes take place with high quantum yields and without further side reactions Therefore, in contrast to most other chromophores, a number of isomerization cycles can be carried out without material destruction All these effects have been widely addressed in the literature Since the pioneer work on photoinduction of optical anisotropy in photosensitive organic materials (Weigert, 1929), the dynamic photoorientation in azobenzene-containing viscous solutions (Makushenko et al, 1971) and dye-polymer blends (Gibbson et al, 1991; Todorov et al, 1984), and the stable anisotropy in functionalized glassy polymers (Eich et al, 1987) have been studied Typical optical applications of the photoinduced order include polarization elements (Petrova et al.

napms(1000);

[Bpm02]

, 2003), diffraction optical elements (Martinez-Ponce et al, 2004), waveguides (Karimi-Alavijeh et al, 2008; Luo et al, 2007), optical storage (Nedelchev et al, 2003; Hagen and Bieringer, 2001; Sabi et al, 2001), all-optical switching (Luo et al, 2005), multiplexing (Ilieva et al, 2005), alignment of liquid crystals (Ichimura, 1996; Ichimura et al, 1994) and bulk alignment of liquid crystalline polymers (Zen et al, 2002; Rosenhauer et al, 2001; Han et al, 2000; Fischer et al, 1997; Stumpe et al, 1991), and orientation of further functional groups in liquid crystalline (LC) polymers (Rosenhauer et al, 2005) Repeated E Z isomerization may also result in a translation motion of the molecules This motion becomes manifested on spatially inhomogeneous irradiation The phenomenon has been known as a light-driven mass transport or, with.

causes program execution to pause for one whole second. The statement:

napms(100);

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